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Spontaneous combustion is real and can be a big problem. It can occur
without the material being volatile. My experience with spontaneous combustion occured when we had our hardwood floors refinished. We had just moved into the house and had a garage full of cardboard boxes, some full of things, and others broken down and stacked. The people who were refinishing the floors placed the sanding dust in a bag in a garbage can in the garage. My wife was in the family room and smelled smoke. When I went into the garage it was filled with smoke. Fortunately I was there when it occured and was able to get the can out of the garage and get the fire extinguished. The only loss was the garbage can. I have often wandered what could have occured. Me wrote: In article , "Roger Long" wrote: We all grew up hearing about the danger of oily rags. It was linseed oil they were talking about, not motor oil. Now that I (hopefully) will be rubbing oil on teak for the rest of my natural life, I expect to producing a lot of these little incendiary bombs. How much of a danger are these left over rags? Is it something that happens just once in a blue moon when a bunch are left in the corner of a shop for a long time in hot weather? If the phone rings and I forget to take one to the dumpster, is it "Good by" boat? If I do toss them in the dumpster, am I at risk of starting a big fire in my favorite marina or boatyard. Is there an approved way of storing or disposing of linseed oil rags? Inquiring mind wants to know. From a chemist's point of view, it is a danger, but not a significant one in most circumstances. Spontainious Combustion can, and does, occure with oily rags, stacked in a pile, with little or no airflow, where heat can build up, due to chemical breakdown of the adsorbing material, by properties in the oils adsorbed. It is a fairly rare occurance, mostly due to folks having been told, many times, of the possibilities, and keeping things cleaned up. Flashpoint Temps for most oils are fairly high and the required heat buildup doesn't happen, but if conditions are right, Yea it can be a BIG Deal..... Me a NitroOrganic Chemist, in a past life....... |
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