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#1
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One thing with ethanol is that the stuff contains oxygen atoms along with
the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
#2
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The oxygen tends to lean the mixture entering the engine.
why do you think that? ethanol has a different fuel/air mixture ratio than gas/air, so needs different jets. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. race engines did it for years. |
#3
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Part of problem is that the gas formula isn't consistent across the country.
Non attainment areas have a different formula than say, rural Nebraska. The Atlantic coast might have yet another regional formula. A production item such as a carbureted outboard or inboard marine engine is a "one size fits all applications" product. It works great in some areas and not so great in others. Since those carbs are designed for an average gas formula (or for whatever standard the engineers has chosen) it is impossible to set them optimum when the gas supply is different from that original standard. My comments are aimed at productions engines rather than something more custom such as a race engine. I have seen rejetting offered as a manufacture's solution in the past but don't recall seeing that recently. A person could experiment with the jets try to get an improvement. With the stalling problem, such as what the original poster had, rejetting might not cure that problem. Those low speed circuits are partially controlled by the size of drilled passageways, not something readily adjustable. "JAXAshby" wrote in message ... The oxygen tends to lean the mixture entering the engine. why do you think that? ethanol has a different fuel/air mixture ratio than gas/air, so needs different jets. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. race engines did it for years. |
#4
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I find it highly unlikely that there are no Oxygen (O) atoms in gas....
Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
#5
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Matt,
Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) Matt Lang wrote: I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
#6
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Hi Matt,
Sorry, but I agree with Matt. Lotsa oxygen, but an organic chemist could help us about the locations that they are stuck on. Suspect that is what people are talking about with oxygenated fuels. surfnturf "Matt Colie" wrote in message ... Matt, Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) Matt Lang wrote: I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
#7
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Uhhh, kinda embarrassed. Too long since high school, should have done my
research before spouting off... I'll back the other Matt now. Cs&Hs, no Os until you get into the additives etc. Been fooling around with wood chemistry too much. surfnturf snip the embarassment "Matt Colie" wrote in message ... Matt, Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) |
#8
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#9
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#10
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dood, rather poor googling on your part. "octane", a physical fact, and
"octane rating", a concept, are not hardly the same thing. (modervador) Date: 9/27/2004 1:46 PM Eastern Daylight Time Message-id: (JAXAshby) wrote in message ... do a google (if you are capable) on the chemical makeup of octane and see how many oxygen atoms you find. Or you could look up the octane rating of methanol (about 100 on the (R+M)/2 scale) and its chemical formula (CH3OH) and note that a liquid fuel with a high octane rating can have as many oxygens as carbons. The octane number on the pump does not tell you how much "real octane" is in the gasoline. Extra credit exercise: look up octane numbers for "normal octane", "normal heptane" and "iso-octane" (a.k.a. 2,2,4-trimethyl pentane). %mod% |
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