Home |
Search |
Today's Posts |
#21
![]()
posted to rec.boats
|
|||
|
|||
![]()
Jeff Rigby wrote:
Not that weak. If you take a distilled water and left it open pH goes down from 7 to about 5.7 - just because of the presence of dissolved carbon dioxide. PH changes from 7, in other words from 5-9 in distilled water take very little acid or base, in other words it's a very weak acid or base. Remember that this change takes place in the presence of only about 380 ppmv of CO2 in the air. Increase amount of CO2 in the atmosphere and the change will be higher. That doesn't mean carbonic acid is not a weak one, you just don't need a strong acid to change pH when you have solution close to pH 7. Borek -- http://www.chembuddy.com http://www.ph-meter.info |
#22
![]()
posted to rec.boats
|
|||
|
|||
![]()
basskisser wrote:
Dan wrote: basskisser wrote: NOYB wrote: "basskisser" wrote in message egroups.com... .... accumulation of carbon dioxide, methane and other heat-trapping greenhouse gases in the atmosphere - byproducts of power plants, automobiles and other fossil fuel burners. Carbon dioxide and methane? I thought those were products of oxygen-breathing mammals and flatuating cows. I already predicted what you'd say. Cite? Infatuation.... Infatuation.... It's making Dan crazy.... It's driving him CRAAAAZY....... Every single thread........ Every single post I make..... Dan's right there trying to smell my ass! Now that's CHILDISH!! |
#23
![]()
posted to rec.boats
|
|||
|
|||
![]() "Dan" wrote in message nk.net... basskisser wrote: Dan wrote: basskisser wrote: NOYB wrote: "basskisser" wrote in message legroups.com... .... accumulation of carbon dioxide, methane and other heat-trapping greenhouse gases in the atmosphere - byproducts of power plants, automobiles and other fossil fuel burners. Carbon dioxide and methane? I thought those were products of oxygen-breathing mammals and flatuating cows. I already predicted what you'd say. Cite? Infatuation.... Infatuation.... It's making Dan crazy.... It's driving him CRAAAAZY....... Every single thread........ Every single post I make..... Dan's right there trying to smell my ass! Now that's CHILDISH!! I have the idiot KF'd.. I suspect he posts comments to my posts here on a regular basis. Perhaps you can confirm this. If my hunch is correct, he is living in a glass house. ;-) |
#24
![]()
posted to rec.boats
|
|||
|
|||
![]() wrote in message oups.com... Jeff Rigby wrote: Not that weak. If you take a distilled water and left it open pH goes down from 7 to about 5.7 - just because of the presence of dissolved carbon dioxide. PH changes from 7, in other words from 5-9 in distilled water take very little acid or base, in other words it's a very weak acid or base. Remember that this change takes place in the presence of only about 380 ppmv of CO2 in the air. Increase amount of CO2 in the atmosphere and the change will be higher. That doesn't mean carbonic acid is not a weak one, you just don't need a strong acid to change pH when you have solution close to pH 7. Borek -- http://www.chembuddy.com http://www.ph-meter.info That's like saying water is a solvent and it dissolves most compounds because the hydrogen and oxygen molecule's geometry lends itself to tearing apart most compounds. We should be concerned with water too. In fact it's not the carbon dioxide that creates the acid, it's water. Without water carbon dioxide is not an acid. I'm not disagreeing with your comments, I find them VERY enlightening. Following is typical household chemicals and their Ph ranking: 1 Stomach Fluids 2 Lemon Juice 3 Vinegar 4 Tomatoes 5 Coffee 6 Milk 7 Pure Water 8 Blood 9 Baking Soda 10 Borax 11 Rolaids, Tums 12 Household Ammonia 13 Bleach 14 Lye |
#25
![]()
posted to rec.boats
|
|||
|
|||
![]()
Jeff Rigby wrote:
Not that weak. If you take a distilled water and left it open pH goes down from 7 to about 5.7 - just because of the presence of dissolved carbon dioxide. PH changes from 7, in other words from 5-9 in distilled water take very little acid or base, in other words it's a very weak acid or base. Remember that this change takes place in the presence of only about 380 ppmv of CO2 in the air. Increase amount of CO2 in the atmosphere and the change will be higher. That doesn't mean carbonic acid is not a weak one, you just don't need a strong acid to change pH when you have solution close to pH 7. That's like saying water is a solvent and it dissolves most compounds because the hydrogen and oxygen molecule's geometry lends itself to tearing apart most compounds. We should be concerned with water too. In fact it's not the carbon dioxide that creates the acid, it's water. Without water carbon dioxide is not an acid. Water dissociates creating the same amounts of H+ and OH- ions. First are connected with solution acidity, the latter with solution basicity. Thus water is acidic and basic - to the same extent - at the same time. That's why pure water is neutral. Almost every substance you can dissolve will change pH of the solution, just sometimes this change is unmeasurable. CO2 is so called acid anhdyride (just like SO3, P2O5 or N2O5 oxides) - it reacts with water to create carbonic acid, which in turns dissociate and acidifies the solution. Other anhydrides listed create stable acids (known as strong mineral acids - sulfuris, nitric and phosphoric). Trick is, carbonic acid is very unstable, thus it concentration in water is very low, much lower than the concentration of CO2. In fact there are papers that suggest that carbonic acid is much stronger than it is commonly believed, just - as its concentration is very low - measurable effect (ie pH change) is low. Trick is, if you want to calculate pH of CO2 saturated solution you have to deal with at least two reactions - first being carbonic acid creation, second its dissociation. You know only how much CO2 is present and what is solution pH - these are controllable/measurable. But the "internal workings" - ie carbonic acid creation/carbonic acid dissociation - are seen as one step with one equilibrium constant which can not be split without additional data. But that's completely OT here ![]() I'm not disagreeing with your comments, I find them VERY enlightening. Following is typical household chemicals and their Ph ranking: Note: pH, not Ph. 1 Stomach Fluids 2 Lemon Juice 3 Vinegar 4 Tomatoes 5 Coffee 6 Milk 7 Pure Water 8 Blood 9 Baking Soda 10 Borax 11 Rolaids, Tums 12 Household Ammonia 13 Bleach 14 Lye Yup. Classical list shown whenever pH scale is discussed: http://www.chembuddy.com/?left=pH-ca...right=pH-scale http://www.ph-meter.info/pH-scale also wiki and many *.edu sites. and so on ![]() Other solutions have pH that can vary, blood pH doesn't change much (see my other post about panting somewhere in this thread). Borek -- http://www.chembuddy.com http://www.ph-meter.info |
#26
![]()
posted to rec.boats
|
|||
|
|||
![]() wrote in message oups.com... Jeff Rigby wrote: Not that weak. If you take a distilled water and left it open pH goes down from 7 to about 5.7 - just because of the presence of dissolved carbon dioxide. PH changes from 7, in other words from 5-9 in distilled water take very little acid or base, in other words it's a very weak acid or base. Remember that this change takes place in the presence of only about 380 ppmv of CO2 in the air. Increase amount of CO2 in the atmosphere and the change will be higher. That doesn't mean carbonic acid is not a weak one, you just don't need a strong acid to change pH when you have solution close to pH 7. That's like saying water is a solvent and it dissolves most compounds because the hydrogen and oxygen molecule's geometry lends itself to tearing apart most compounds. We should be concerned with water too. In fact it's not the carbon dioxide that creates the acid, it's water. Without water carbon dioxide is not an acid. Water dissociates creating the same amounts of H+ and OH- ions. First are connected with solution acidity, the latter with solution basicity. Thus water is acidic and basic - to the same extent - at the same time. That's why pure water is neutral. I understood that water does NOT disassociate, it's a very stable and strong bond, EXTREMELY strong bond, it's equalibrium reaction has very few disassocited ions. It's geometry, were oxygen and hydorgen atoms are placed in the molecule allow the water moleule to have a strong charge at each end where the oxygen has a - charge and the Hydrogen has + charge. It ionizes molecules because of this GEOMETRY not because water disassociates. It's because of this geometry that water has unique properties when frozen. Cold water sinks but ice floats!. Pure water can not carry a charge! Try for yourself, put two electrodes in distilled water and try to run a current thru water, you won't get one untill you introduce a compound that can be ionized to carry the current. If pure water can not carry a charge then it is not disassociated. You can crack the water molecule with enough voltage but it doesn't ionize it cracks and releases hydrogen gas and oxygen gas. |
#27
![]()
posted to rec.boats
|
|||
|
|||
![]()
Jeff Rigby wrote:
Water dissociates creating the same amounts of H+ and OH- ions. First are connected with solution acidity, the latter with solution basicity. Thus water is acidic and basic - to the same extent - at the same time. That's why pure water is neutral. I understood that water does NOT disassociate, it's a very stable and strong bond, EXTREMELY strong bond, it's equalibrium reaction has very few disassocited ions. H2O - H+ + OH- You are right that equilibrium for this reaction is far to the left - ie water is dissociated only slightly, but nonetheless it is dissociated and it can't be neglected whenever we are talking about pH of solutions, especially those close to the neutral. Note, that pH = -log([H+]) - if pure water has pH = 7 there MUST be some free H+ ions in the solution, and they come just from water autodissociation. If you think that 10^-7 is so low concentration that it can be neglected, think about pH indicators - some of them change color just because concentration of H+ changes from 10^-7 to 10^-8 mol/L. So these pretty small changes in concentrations can produce large effects. Which is - BTW - one of the reasons why some people want to precisely monitor pH of oceans ![]() It's geometry, were oxygen and hydorgen atoms are placed in the molecule allow the water moleule to have a strong charge at each end where the oxygen has a - charge and the Hydrogen has + charge. Yep, water molecule is a dipole. It ionizes molecules because of this GEOMETRY not because water disassociates. These are two completely different things. Autodissociation of water is one thing, dissociation of salts - induced by water properties - is second thing. Don't mix them. Pure water can not carry a charge! Try for yourself, put two electrodes in distilled water and try to run a current thru water, you won't get one untill you introduce a compound that can be ionized to carry the current. If pure water can not carry a charge then it is not disassociated. You can crack the water molecule with enough voltage but it doesn't ionize it cracks and releases hydrogen gas and oxygen gas. Ultrapure water has very high resistivity, something like 18MOhm/cm, that's right. But it doesn't mean it is not dissociating ![]() Borek -- http://www.chembuddy.com http://www.ph-meter.info |
#28
![]()
posted to rec.boats
|
|||
|
|||
![]() "scbafreak via BoatKB.com" u25927@uwe wrote in message news:690cec9d084bd@uwe... yes, they had to find some other "threat" I'm Curious. Who are "They" and what could "They" possibly have to gain from making this stuff up? Yes, lets list who they are and maybe we can find out why they are biased against developing nations. -- Message posted via http://www.boatkb.com |
Reply |
Thread Tools | Search this Thread |
Display Modes | |
|
|
![]() |
||||
Thread | Forum | |||
Total Bobsprit Humiliation!!!! | ASA | |||
Smackdown...Bob has no boat | ASA | |||
Turning Pig Poop into Boat Fuel | General | |||
try teasing the ocean's old butcher and Yolanda will attempt you | ASA |