|
Problems with ethanol in fuel
Both of my power boats have developed severe engine hesitation
problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Larry Weiss wrote in message ...
Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? I have experienced some cars also not runnig with ethanol blend ... I dont know the technical reason, but may speculate its different properties dont lead to proper air mix. Aside from that you should never use ethanol fuel in 2 strokes. Matt |
Ethanol, or alcohol, mixes with any water. It's used up here by some in the
winter (auto engines) to pick up any condensation and so on to prevent gas line freeze. So, if the alcohol in the mix becomes saturated (with water), a drop in temperature will cause that water to be dumped, leaving the water in the fuel system ... especially not good in injected engines. If that's what's happening, maybe a water separator mounted close to the engine might be an idea? The dumping of water by saturated ethanol fuel caused by a drop in temperature is a fact ... but a 10% mix ... ??? "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Larry Weiss wrote:
Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." Here's a good compilation of current manufacturer's recommendations. Mercury seems especially against ethanol fuel. http://www.ethanolrfa.org/2003marine.pdf |
So the problem would appear to be water.
"John Wentworth" wrote in message ... Larry Weiss wrote: Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." Here's a good compilation of current manufacturer's recommendations. Mercury seems especially against ethanol fuel. http://www.ethanolrfa.org/2003marine.pdf |
On Tue, 21 Sep 2004 17:36:59 GMT, Larry Weiss
wrote: Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? I wasn't aware it was ten percent, but recently some of the mechanics I know have been running into filter problems. When they drain off the fuel, it smells like alcohol - which would lead me to believe that the combination of ethanol and the alcohol in Dry Gas or it's equivilent is causing most of the problems. In CT, I haven't had a problem with my Ranger, but the I've have to change my water seperation filters twice this year. Got a feeling that it's the ethanol in the gas I get at Brewers. I can only speak Johnson/Evinrude, but they are really anti-ethanol for two stroke systems. I'm not sure why. Take care. Tom "The beatings will stop when morale improves." E. Teach, 1717 |
It attracts water and when it reaches saturation the water dumps out. Not
so good in a boat as i's hard to avoid water. If you can remove the sending unit from your fuel tank and see if it has water in the bottom. Get it out if it does. Drain all your fuel filters regularly. Keep the water out and you'll have less trouble. But it's hard to do. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Over here in Western Pennsylvania I use Sunoco 93 octane and haven't had any
problems. I used the same fuel since 99 in my Mercury OB. 10%, don't think so as the max is no more than 5% from Sunoco. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Nope 10% ethanol mixed with gasoline will result in the water component
forming into an emulsified form which doesnt separate readily. Actually the additional water content helps increase the "octane" number, and also helps to clean the piston ring grooves, blows the carbon out of the combustion chamber, etc. Some engines (back in 'muscle car days') used water injection to boost power output while helping to cool the combustion chambers. article gers.com, Bowgus wrote: Ethanol, or alcohol, mixes with any water. It's used up here by some in the winter (auto engines) to pick up any condensation and so on to prevent gas line freeze. So, if the alcohol in the mix becomes saturated (with water), a drop in temperature will cause that water to be dumped, leaving the water in the fuel system ... especially not good in injected engines. If that's what's happening, maybe a water separator mounted close to the engine might be an idea? The dumping of water by saturated ethanol fuel caused by a drop in temperature is a fact ... but a 10% mix ... ??? "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
"Woodchuck" wrote in message ...
Over here in Western Pennsylvania I use Sunoco 93 octane and haven't had any problems. I used the same fuel since 99 in my Mercury OB. 10%, don't think so as the max is no more than 5% from Sunoco. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." Ok here some fact about alcohol addition to fuel: For a long time people have sometimes added a bit of alcohol to the gasoline in areas where water might get into the gas tank. The water does not mix with the gasoline and in cold climates can freeze in the gas line and in warmer climates prevent the engine from starting. Water is not a good fuel. Addition of the alcohol will cause formation of a ternarty mixture with the water and the gasoline and avoid the water from separating out. More recnetly in some states like california the EPA in order to reduce engine pollution the government has mandated the use of Oxygenated fuels. This is gasoline that has up to 10% alcohol added to make the gasoline burn cleaner. The 10% number comes from an agreement of automobile engine manufacturers who have agreed that up to 10 % the engine is not harmed and no special adjustment is required. With more than 10% alcohol the power of the engine is reduced and parts may suffer. In Brazil some cars use pure alcohol, these are special engines and people don't like them because they have no power ( I used to live there and had a car with an alcohol engine) For these reasons I don't think that poor running of an engine with a gasoline/10% alcohol is the problem. Water tends to cause starting problems but once the engine is running at high speed the water tends to disperse ( not dissolve ) and go through the engine with the gasoline. There may be several reasons for the stalling problem. Most likely the engines are starved of fuel when revved. Since it occurs on both engines it may be a simple as some blockage in the fuel line that allows some fuel to get through, enough for idle, but not enough for a high rev. S I would look for the problem in the fuel filters, fuel line, fuel pump etc |
On Wed, 22 Sep 2004 04:26:52 GMT, Rich Hampel
wrote: Nope 10% ethanol mixed with gasoline will result in the water component forming into an emulsified form which doesnt separate readily. Actually the additional water content helps increase the "octane" number, and also helps to clean the piston ring grooves, blows the carbon out of the combustion chamber, etc. Some engines (back in 'muscle car days') used water injection to boost power output while helping to cool the combustion chambers. I had forgotten about that. Must be getting old. Take care. Tom "The beatings will stop when morale improves." E. Teach, 1717 |
One thing with ethanol is that the stuff contains oxygen atoms along with
the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
The oxygen tends to lean the mixture entering the engine.
why do you think that? ethanol has a different fuel/air mixture ratio than gas/air, so needs different jets. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. race engines did it for years. |
"Larry Weiss" wrote in message
... Both of my power boats have developed severe engine hesitation.... .... blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. Problems we had in motorcycles involved water. Seems that while gas and ethonol mix fine and ethanol and water mix that ethanol saturated with water doesn't mix with gas nor burn well. |
Larry,
As so often happens in these groups, there is a good deal of less than complete data. After several decades of working in the test labs of Detroit let me fill in some of the problems. Old issue: Alcohol is a solvent for the "Permatex" that used to seal two-stroke crankcases. This would allow charge mixture to leak out, air to leak in during the cycle and the engine would go lean and self distruct. There was also an issue raised with the alcohol interfering with the lubricity of the ashless oil causing a breakdown under load. I never saw this verfied and was told by a lubricant supplier that it was simply false. This would make sense becuase the engine damage that I surveyed was all piston damage most likely the result of lean mixture. Fix - Use an alcohol resistant silcone base RTV sealant during assembly. Known issue: All elastomers have some absortion rate of almost all liquids. It is additive. So, if Hexane make a 4% swell, and butane makes a 2% swell then expect winter pump gasoline to cause 6% swell. Alcohol swell is typically 3-4%, so it added to the fuel you should now expect a 10% swell. That will FU (make less than optimal) a rubber tipped needle and seat of an old carburetor float valve system in fine style. Fix - Go find a Grose Jet to replace the rubber tipped needle and seat. These were made for out labe by a shop in RI (Providence - I think). If the neat guy that runs the shop is still there, he has data for most things and can make what you have data for. - Not cheap - Very Good Little known issue: But, touched on by one poster. The F/A will be differnet for an -OH (the family of alcohols) blend fuel than it is with pump grade non-OH blended fuel. This can and often did cause drivability and performance issues. Modern cars correct for this on the fly (not goingthere now). Fix - Older engines can not do this automaticly, but can be corrected for the 12-20$us that a box of carburetor jets will cost (you can stiil buy at speed shops). Upsize the main jet(s) in the carburetor until the engine runs as it should. Unfortunately, this was much easier to do in a engine dynamometer test room that I might be in a boat, but I have done it and it takes some patience and persistance. Good Luck Matt Colie Larry Weiss wrote: Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
On Wed, 22 Sep 2004 17:06:31 -0400, Matt Colie
wrote: ~~ good stuff snipped ~~ Unfortunately, this was much easier to do in a engine dynamometer test room that I might be in a boat, but I have done it and it takes some patience and persistance. Dude!!! Good info. Thanks for the post. Take care. Tom "The beatings will stop when morale improves." E. Teach, 1717 |
Part of problem is that the gas formula isn't consistent across the country.
Non attainment areas have a different formula than say, rural Nebraska. The Atlantic coast might have yet another regional formula. A production item such as a carbureted outboard or inboard marine engine is a "one size fits all applications" product. It works great in some areas and not so great in others. Since those carbs are designed for an average gas formula (or for whatever standard the engineers has chosen) it is impossible to set them optimum when the gas supply is different from that original standard. My comments are aimed at productions engines rather than something more custom such as a race engine. I have seen rejetting offered as a manufacture's solution in the past but don't recall seeing that recently. A person could experiment with the jets try to get an improvement. With the stalling problem, such as what the original poster had, rejetting might not cure that problem. Those low speed circuits are partially controlled by the size of drilled passageways, not something readily adjustable. "JAXAshby" wrote in message ... The oxygen tends to lean the mixture entering the engine. why do you think that? ethanol has a different fuel/air mixture ratio than gas/air, so needs different jets. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. race engines did it for years. |
I find it highly unlikely that there are no Oxygen (O) atoms in gas....
Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Matt,
Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) Matt Lang wrote: I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Hi Matt,
Sorry, but I agree with Matt. Lotsa oxygen, but an organic chemist could help us about the locations that they are stuck on. Suspect that is what people are talking about with oxygenated fuels. surfnturf "Matt Colie" wrote in message ... Matt, Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) Matt Lang wrote: I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
kennie be a b/sing agin.
I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
|
|
schlackoff, you are even a worse chemist than you are a sailor. I suggest you
ask some high school kid to explain what happens to octane when you remove the oxygen. go stand in the corner. (Steven Shelikoff) Date: 9/23/2004 11:30 PM Eastern Daylight Time Message-id: On 23 Sep 2004 12:12:48 -0700, (Matt Lang) wrote: I find it highly unlikely that there are no Oxygen (O) atoms in gas.... There are, but tiny amounts. Gasoline is mostly hydrocarbon molecules, which like the name implies, is only hydrogen and carbon atoms. There are many of different types of hydrocarbon molecules in typical gasoline. However, there are also trace amounts of other compounds in there, some of which contain oxygen atoms as well as sulphur, nitrogen, some metals ... Steve |
JAXAshby wrote:
schlackoff, you are even a worse chemist than you are a sailor. I suggest you ask some high school kid to explain what happens to octane when you remove the oxygen. go stand in the corner. You should cut back on the amount of ethanol you drink, Jaxass. -- We today have a president of the United States who looks like he is the son of Howdy Doody or Alfred E. Newman, who isn't smarter than either of them, who is arrogant about his ignorance, who is reckless and incompetent, and whose backers are turning the United States into a pariah. What, me worry? |
With the stuff you get from the gas pump, ya, there is oxygen in the
formula. It is being put there by design for pollution purposes (EPA mandates) and for economic reasons (sometimes its cheaper to blend straight gas with something). At a chemical level, gasoline does not contain oxygen. The key word is formula. If only the powers that be would quit changing the formula. Carbs are limited range animals that can't fully handle all that difference. Engines demand a specific ratio of hydrocarbons to oxygen to produce optimum burn (or a richer mixture for optimum power). With a constantly changing formula, it becomes harder or impossible to adjust a carb to produce that optimum. For more info on gas see http://auto.howstuffworks.com/gasoline1.htm http://www.newton.dep.anl.gov/askasc.../chem99658.htm http://www.smokemup.com/tech/fuels.php "Matt Lang" wrote in message om... I find it highly unlikely that there are no Oxygen (O) atoms in gas.... Matt "Ken" wrote in message ... One thing with ethanol is that the stuff contains oxygen atoms along with the hydrogen and carbon atoms, where as straight gasoline is hydrogen and carbon only. The oxygen tends to lean the mixture entering the engine. No matter what carb setting you apply after that, the air/fuel ratio never gets back to what it was. A lean mixture will burn hotter and more readily creates detonation and preignition (4 cylinders inboards tend to have dieseling problems with the stuff). It can also cause stalling problems. With cars the oxygenated fuels tends to work ok as the computers and sensors keep a good control. With marine engines its a problem. "Larry Weiss" wrote in message ... Both of my power boats have developed severe engine hesitation problems. They run okay at idle but sputter and stall when revved. My mechanics have complained that they are seeing this problem left and right - and are blaming it on the gasoline, which around here (Long Island, NY) now contains 10% ethanol. I know ethanol is not good for rubberized fuel lines, but did not know it caused running problems (unless the fuel lines are deteriorating and clogging). The gas in each boat was purchased at a different fuel dock. If my mechanics are correct, this is a serious regional (national?) problem. Anyone else experiencing difficulty? Any comments or suggestions? How can we get gasoline without ethanol in it? How is the marine industry addressing this? Larry Weiss "...Ever After!" "a little after..." |
Uhhh, kinda embarrassed. Too long since high school, should have done my
research before spouting off... I'll back the other Matt now. Cs&Hs, no Os until you get into the additives etc. Been fooling around with wood chemistry too much. surfnturf snip the embarassment "Matt Colie" wrote in message ... Matt, Believe it. Of that stuff you call gasoline (those things that come of the the distillation between 100 and 200 degF) there is no chemical formulae. It is all organic hydrocarbon and the best they can due is provide a hydrogen/cardon ratio. And that is Gasoline... What gets added after that is anybody's bet. It isn't Tetraethyllead Pb(C2H5)4 anymore, but it can be any portion of a chemical alphabet soup (like MTBE, TAME and ETBE) with out even getting to the oxygenates. Most what was added in teh pst improved the octane rating. now what is added is largely to improve the combustion efficiency. Matt Colie (Engine Lab Rat -ret) |
|
|
dood, rather poor googling on your part. "octane", a physical fact, and
"octane rating", a concept, are not hardly the same thing. (modervador) Date: 9/27/2004 1:46 PM Eastern Daylight Time Message-id: (JAXAshby) wrote in message ... do a google (if you are capable) on the chemical makeup of octane and see how many oxygen atoms you find. Or you could look up the octane rating of methanol (about 100 on the (R+M)/2 scale) and its chemical formula (CH3OH) and note that a liquid fuel with a high octane rating can have as many oxygens as carbons. The octane number on the pump does not tell you how much "real octane" is in the gasoline. Extra credit exercise: look up octane numbers for "normal octane", "normal heptane" and "iso-octane" (a.k.a. 2,2,4-trimethyl pentane). %mod% |
|
|
|
the octane rating of normal octane, ... is, less than zero.
wtf??? |
|
yo-yo, octane has -- be definition -- an octane rating of 100. check it out.
(modervador) Date: 9/30/2004 12:21 PM Eastern Daylight Time Message-id: (JAXAshby) wrote in message ... the octane rating of normal octane, ... is, less than zero. wtf??? That is correct. Less than zero. Less than the rating assigned to normal heptane. I gave you a big hint when I said to look up octane numbers for "normal octane", "normal heptane" and "iso-octane" (a.k.a. 2,2,4-trimethyl pentane). Here's another hint (in form of questions): which is better as diesel fuel, octane or cetane? Which has higher octane number, heptane or propane? Can we make any generalizations about long vs. short chain alkanes and their branched isomers? %mod% |
here you, yo-yo. http://www.encyclopedia.com/html/o1/octanenu.asp
an explaination even you can understand as to what the "octane rating" of octane is. the octane rating of normal octane, ... is, less than zero. wtf??? That is correct. Less than zero. Less than the rating assigned to normal heptane. I gave you a big hint when I said to look up octane numbers for "normal octane", "normal heptane" and "iso-octane" (a.k.a. 2,2,4-trimethyl pentane). Here's another hint (in form of questions): which is better as diesel fuel, octane or cetane? Which has higher octane number, heptane or propane? Can we make any generalizations about long vs. short chain alkanes and their branched isomers? %mod% |
|
odor, I ain't gonna check out anything you say. you have already shown
yourself to be a fraud with your ficitional statement that alcohol in small amounts added to gasoline increases the octane rating by substantial amounts, and the EPA required gas companies add alcohol to gas because carb's engines run better at engine startup and thus the EPA saves the ass of automobile companies once again. other readers, please note odor's fraud address, the same address as used by a couple dozen frauds here. (modervador) Date: 10/1/2004 8:04 AM Eastern Daylight Time Message-id: |
All times are GMT +1. The time now is 06:07 AM. |
|
Powered by vBulletin® Copyright ©2000 - 2024, Jelsoft Enterprises Ltd.
Copyright ©2004 - 2014 BoatBanter.com