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"Mark" wrote in news:1156831412.903466.125420
@b28g2000cwb.googlegroups.com: Sulfation which drops to the bottom of the battery case does not decrease battery capacity. There's space at the bottom of the battery for just that reason. The battery's service life is decreased; ultimately enough crud will drop to the bottom of the battery to short it out. This is just not true because the capacity of a lead-acid battery is caused by the acid charge in that battery. "Discharged" means, quite simply, that we've run out of acid to eat the lead. Lead Sulphate that drops out of suspension and cannot be recovered from the bottom of the battery USES UP the acid charge, making that acid charge unrecoverable. As it sulphates (or sulfates, I gotta go look that up some time) more and more the "fully charged" specific gravity, the measure of the acid intensity in the electrolyte, will fail to come up to 1.260-1.280 of a new battery. The sulfated (sulphated??) battery will run OUT of acid on discharge faster. You've lost capacity. "Dead Cell" isn't really dead. It's just that its acid load has been converted "mostly" to lead sulfate and can no longer be charged. Now, before we get to the plates-have-been-holed-and-warped state, you can ADJUST the acid load on a FULLY CHARGED battery back up to recover the lost acid to sulfation. VERY SLOWLY adding sulphuric acid to the electrolyte, agitating or simply waiting for a day, then adding more as you continue to test specific gravity with your TEMPERATURE COMPENSATED real hydrometer, can recover a low capacity cell you haven't let go too far. (This sorta happens when some IDIOT drops an aspirin tablet, 2- (acetyloxy)benzoic acid, into the poor battery he's trying to destroy.) He gets a momentary boost in voltage and thinks he's fixed it. He hasn't. It's this sulfation problem of lead acid batteries the manufacturers depend on to produce a steady stream of sales to the same people, over and over. Sales have gone up since we convinced them a gelcell or AGM battery that CANNOT precipitate its crystals is worth $300. When these stationary-electrolyte batteries sulfate, the sulfate crystals stay in place. Of course, great for manufacturers, there isn't going to be any smartass adjusting the gravity to save it if we seal it all up and make it "maintenance free", now, is there? -- There's amazing intelligence in the Universe. You can tell because none of them ever called Earth. |
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