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#1
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Interesting Lead Acid Battery facts
I found this information in a e-book called "Batteries in a Portable
World" by Buchmann. In our ongoing watered golf cart vs. expensive maintenance-free gauze battery discussion, there are some very revealing facts the author points out that I'm sure the battery sales people wouldn't want you to look at too closely... Sorry for the wordwrapping nonsense I can't seem to stop.... It says: "The Lead Acid Battery Invented by the French physician Gaston Planté in 1859, lead acid was the first rechargeable battery for commercial use. Today, the flooded lead acid battery is used in automobiles, forklifts and large uninterruptible power supply (UPS) systems. During the mid 1970s, researchers developed a maintenance-free lead acid battery, which could operate in any position. The liquid electrolyte was transformed into moistened separators and the enclosure was sealed. Safety valves were added to allow venting of gas during charge and discharge. Driven by diverse applications, two designations of batteries emerged. They are the sealed lead acid (SLA), also known under the brand name of Gelcell, and the valve regulated lead acid (VRLA). Technically, both batteries are the same. No scientific definition exists as to when an SLA becomes a VRLA. (Engineers may argue that the word ‘sealed lead acid’ is a misnomer because no lead acid battery can be totally sealed. In essence, all are valve regulated.) The SLA has a typical capacity range of 0.2Ah to 30Ah and powers portable and wheeled applications. Typical uses are personal UPS units for PC backup, small emergency lighting units, ventilators for health care patients and wheelchairs. Because of low cost, dependable service and minimal maintenance requirements, the SLA battery is the preferred choice for biomedical and health care instruments in hospitals and retirement homes. The VRLA battery is generally used for stationary applications. Their capacities range from 30Ah to several thousand Ah and are found in larger UPS systems for power backup. Typical uses are mobile phone repeaters, cable distribution centers, Internet hubs and utilities, as well as power backup for banks, hospitals, airports and military installations. Unlike the flooded lead acid battery, both the SLA and VRLA are designed with a low over-voltage potential to prohibit the battery from reaching its gas-generating potential during charge. Excess charging would cause gassing and water depletion. Consequently, the SLA and VRLA can never be charged to their full potential. Among modern rechargeable batteries, the lead acid battery family has the lowest energy density. For the purpose of analysis, we use the term ‘sealed lead acid’ to describe the lead acid batteries for portable use and ‘valve regulated lead acid’ for stationary applications. Because of our focus on portable batteries, we focus mainly on the SLA. The SLA is not subject to memory. Leaving the battery on float charge for a prolonged time does not cause damage. The battery’s charge retention is best among rechargeable batteries. Whereas the NiCd self-discharges approximately 40 percent of its stored energy in three months, the SLA self-discharges the same amount in one year. The SLA is relatively inexpensive to purchase but the operational costs can be more expensive than the NiCd if full cycles are required on a repetitive basis. The SLA does not lend itself to fast charging — typical charge times are 8 to 16 hours. The SLA must always be stored in a charged state. Leaving the battery in a discharged condition causes sulfation, a condition that makes the battery difficult, if not impossible, to recharge. Unlike the NiCd, the SLA does not like deep cycling. A full discharge causes extra strain and each discharge/charge cycle robs the battery of a small amount of capacity. This loss is very small while the battery is in good operating condition, but becomes more acute once the performance drops below 80 percent of its nominal capacity. This wear-down characteristic also applies to other battery chemistries in varying degrees. To prevent the battery from being stressed through repetitive deep discharge, a larger SLA battery is recommended. Depending on the depth of discharge and operating temperature, the SLA provides 200 to 300 discharge/charge cycles. The primary reason for its relatively short cycle life is grid corrosion of the positive electrode, depletion of the active material and expansion of the positive plates. These changes are most prevalent at higher operating temperatures. Applying charge/discharge cycles does not prevent or reverse the trend. There are some methods that improve the performance and prolong the life of the SLA. The optimum operating temperature for a VRLA battery is 25°C (77°F). As a rule of thumb, every 8°C (15°F) rise in temperature will cut the battery life in half. VRLA that would last for 10 years at 25°C would only be good for 5 years if operated at 33°C (95°F). The same battery would endure a little more than one year at a temperature of 42°C (107°F). The SLA has a relatively low energy density compared with other rechargeable batteries, making it unsuitable for handheld devices that demand compact size. In addition, performance at low temperatures is greatly reduced. The SLA is rated at a 5-hour discharge or 0.2C. Some batteries are even rated at a slow 20 hour discharge. Longer discharge times produce higher capacity readings. The SLA performs well on high pulse currents. During these pulses, discharge rates well in excess of 1C can be drawn. In terms of disposal, the SLA is less harmful than the NiCd battery but the high lead content makes the SLA environmentally unfriendly. Ninety percent of lead acid-based batteries are being recycled." Most interesting.... No wonder they last longer up north where it's colder than here in the tropics....contrary to the idea of pulling them out of the boat and putting them in a warm place all winter... Looks like they're better off in the boat under the snow! |
#2
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
Larry,
How would you count a charge / discharge cycle according to this article? When I use my two paralleled AGM's to start my little 15 hp diesel, is that a cycle? I don't see how it could be since I sail nearly every day during the summer and my batteries ought to be nearly dead now. If the battery is good for 200 cycles and my draw down is only 10% (In reality, it's probably less than that since my engine lights of almost as quickly as a good car engine) can I expect to get closer to 2000 charging cycles? I feel even better about leaving my batteries in the boat now. Thanks for the article. -- Roger Long |
#3
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
Roger Long wrote:
Larry, How would you count a charge / discharge cycle according to this article? When I use my two paralleled AGM's to start my little 15 hp diesel, is that a cycle? I don't see how it could be since I sail nearly every day during the summer and my batteries ought to be nearly dead now. If the battery is good for 200 cycles and my draw down is only 10% (In reality, it's probably less than that since my engine lights of almost as quickly as a good car engine) can I expect to get closer to 2000 charging cycles? I feel even better about leaving my batteries in the boat now. Thanks for the article. Roger, starting a 15 hp diesel probably takes less than 80 amps for 20 seconds. This is less than half an amp-hour, probably less than one percent of the battery's capacity. Mere noise in charge/discharge cycle space. Chuck ----== Posted via Newsfeeds.Com - Unlimited-Unrestricted-Secure Usenet News==---- http://www.newsfeeds.com The #1 Newsgroup Service in the World! 120,000+ Newsgroups ----= East and West-Coast Server Farms - Total Privacy via Encryption =---- |
#4
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
"Roger Long" wrote in
: How would you count a charge / discharge cycle according to this article? When I use my two paralleled AGM's to start my little 15 hp diesel, is that a cycle? I don't see how it could be since I sail nearly every day during the summer and my batteries ought to be nearly dead now. If the battery is good for 200 cycles and my draw down is only 10% (In reality, it's probably less than that since my engine lights of almost as quickly as a good car engine) can I expect to get closer to 2000 charging cycles? I believe he was referring to drawing down the battery in a deep discharge cycle, not just a burst of starter current. Hell, we'd have to put 4 batteries a year in my car if that were so...(c; A good diesel fires on the 2nd TDC it rolls over. When Dan had the old Hatteras 56, I told him I'd be afraid to jack over the 8v92TAs by hand as they would probably start as soon as something moved. Both those engines you just touched the starter and they popped up running...2-strokes, gotta love 'em. I think the 300 real cycles, using the batteries for lights and loads, then recharging them properly to full charge SLOWLY is quite realistic for lead acid AGMs or Gelcells. I just spent $70 putting 2 new 12AH AGMs in my dock scooter. It's like driving a hot rod! Even at full throttle, the status light stays green as soon as it comes up to speed. The acid soaked gauze gets used up in about 200 cycles in the scooter....less than a year the way I use it all summer. There were very important graphs to study in this report that boaters need to see, especially about charging.... I found the book for free on his website: http://www.buchmann.ca/toc.asp In figure 4-3 on pdf page 61, notice how the 3-stage charging is measured in HOURS, not running the diesel for 30 minutes like boaters dream of. Notice how the current drops very rapidly near the start of the charge, not when the charge is near complete. My assertion of why it's stupid to put a 140 amp alternator on a little sailboat diesel is obvious. The accompanying text: "A multi-stage charger applies constant-current charge, topping charge and float charge (see Figure 4-3). During the constant current charge, the battery charges to 70 percent in about five hours; the remaining 30 percent is completed by the slow topping charge. The topping charge lasts another five hours and is essential for the well-being of the battery. This can be compared to a little rest after a good meal before resuming work. If the battery is not completely saturated, the SLA will eventually lose its ability to accept a full charge and the performance of the battery is reduced. The third stage is the float charge, which compensates for the self-discharge after the battery has been fully charged." See the time in HOURS, not MINUTES? He's especially talking about AGM and Gelcell batteries boaters think are superbatteries because of the awful prices. So, you're looking at charging them for several hours, not just when the charging voltage pops up as is so often the case in a boat trying to get that diesel shut down ASAP...shortening battery life in the process by first overcharging, then not giving the chemistry TIME to charge the cells. To quote the text, again: "The charge algorithm for lead acid batteries differs from nickel-based chemistry in that voltage limiting rather than current limiting is used. Charge time of a sealed lead acid (SLA) is 12 to 16 hours. With higher charge currents and multi-stage charge methods, charge time can be reduced to 10 hours or less. SLAs cannot be fully charged as quickly as nickel-based systems." 10 HOURS, not 30 minutes. Most sailboat captains would have a heart attack....(c; Of course, if you're headed back to the dock to plug in the little 10A chargers...or a mooring with big solar panels or wind charger...that's exactly what happens...HOURS. I still prefer liquid electrolyte to gells and wicks. I can charge them to a full charge and replace any electrolyte that vents. I can also adjust their specific gravity to balance the cells over time to maximize life. "Maintenance Free" just means you can't help them, once they start down. Larry -- Why is it, in any city, all traffic lights act as if they have rotary timers in them, like they did in 1955, and are all set to create maximum inconvenience and block traffic movement, entirely? |
#5
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
The battery power required to start the engine raises a question for me. I
have a Universal 18 in my boat. I have not tried to manually crank it by attaching a handle to the crank shaft, but I have been told that it can be done by hammering a wrench socket onto the shaft, and cranking it with a ratchet. It seems like this would be a good way to conserve battery power if there were a non-destructive way to manually crank the engine. Is there some sort of racheted, removable socket that would fit on the shaft to enable a manual crank, sort of like automobile crank handles at the turn of the century? A little elbow grease might save a tree in the long run. "Larry" wrote in message ... "Roger Long" wrote in : How would you count a charge / discharge cycle according to this article? When I use my two paralleled AGM's to start my little 15 hp diesel, is that a cycle? I don't see how it could be since I sail nearly every day during the summer and my batteries ought to be nearly dead now. If the battery is good for 200 cycles and my draw down is only 10% (In reality, it's probably less than that since my engine lights of almost as quickly as a good car engine) can I expect to get closer to 2000 charging cycles? I believe he was referring to drawing down the battery in a deep discharge cycle, not just a burst of starter current. Hell, we'd have to put 4 batteries a year in my car if that were so...(c; A good diesel fires on the 2nd TDC it rolls over. When Dan had the old Hatteras 56, I told him I'd be afraid to jack over the 8v92TAs by hand as they would probably start as soon as something moved. Both those engines you just touched the starter and they popped up running...2-strokes, gotta love 'em. I think the 300 real cycles, using the batteries for lights and loads, then recharging them properly to full charge SLOWLY is quite realistic for lead acid AGMs or Gelcells. I just spent $70 putting 2 new 12AH AGMs in my dock scooter. It's like driving a hot rod! Even at full throttle, the status light stays green as soon as it comes up to speed. The acid soaked gauze gets used up in about 200 cycles in the scooter....less than a year the way I use it all summer. There were very important graphs to study in this report that boaters need to see, especially about charging.... I found the book for free on his website: http://www.buchmann.ca/toc.asp In figure 4-3 on pdf page 61, notice how the 3-stage charging is measured in HOURS, not running the diesel for 30 minutes like boaters dream of. Notice how the current drops very rapidly near the start of the charge, not when the charge is near complete. My assertion of why it's stupid to put a 140 amp alternator on a little sailboat diesel is obvious. The accompanying text: "A multi-stage charger applies constant-current charge, topping charge and float charge (see Figure 4-3). During the constant current charge, the battery charges to 70 percent in about five hours; the remaining 30 percent is completed by the slow topping charge. The topping charge lasts another five hours and is essential for the well-being of the battery. This can be compared to a little rest after a good meal before resuming work. If the battery is not completely saturated, the SLA will eventually lose its ability to accept a full charge and the performance of the battery is reduced. The third stage is the float charge, which compensates for the self-discharge after the battery has been fully charged." See the time in HOURS, not MINUTES? He's especially talking about AGM and Gelcell batteries boaters think are superbatteries because of the awful prices. So, you're looking at charging them for several hours, not just when the charging voltage pops up as is so often the case in a boat trying to get that diesel shut down ASAP...shortening battery life in the process by first overcharging, then not giving the chemistry TIME to charge the cells. To quote the text, again: "The charge algorithm for lead acid batteries differs from nickel-based chemistry in that voltage limiting rather than current limiting is used. Charge time of a sealed lead acid (SLA) is 12 to 16 hours. With higher charge currents and multi-stage charge methods, charge time can be reduced to 10 hours or less. SLAs cannot be fully charged as quickly as nickel-based systems." 10 HOURS, not 30 minutes. Most sailboat captains would have a heart attack....(c; Of course, if you're headed back to the dock to plug in the little 10A chargers...or a mooring with big solar panels or wind charger...that's exactly what happens...HOURS. I still prefer liquid electrolyte to gells and wicks. I can charge them to a full charge and replace any electrolyte that vents. I can also adjust their specific gravity to balance the cells over time to maximize life. "Maintenance Free" just means you can't help them, once they start down. Larry -- Why is it, in any city, all traffic lights act as if they have rotary timers in them, like they did in 1955, and are all set to create maximum inconvenience and block traffic movement, entirely? |
#6
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
Larry wrote:
Snip In figure 4-3 on pdf page 61, notice how the 3-stage charging is measured in HOURS, not running the diesel for 30 minutes like boaters dream of. Notice how the current drops very rapidly near the start of the charge, not when the charge is near complete. My assertion of why it's stupid to put a 140 amp alternator on a little sailboat diesel is obvious. Snip In fairness, typical automotive chargers are not rated for use with the aggressive, constant-current charging cycles used in popular marine "smart chargers". Replacing the stock alternator with a higher-rated one when switching to a smart charger is not a bad idea, providing engine, pulleys, and belts are also willing. I agree that 30 minutes is not going to restore 50% of capacity on 200 Ah deep-cycle lead acid batteries. With a 140 amp alternator, gasses, venting, etc., permitting, it would take more than an hour. Hard to generalize, but with an adequate alternator, belt, engine speed and charger, it is heat and gassing that ultimately limit the rate at which you can jam amp-hours into a storage battery, and the better smart chargers monitor terminal temperature and fold back current to try to keep things intact. Haven't heard many horror stories of smart chargers destroying batteries. Remember too, even though you recover most of the lost charge quickly through constant-current charging, that last 10-15% is what will take hours to accomplish under typical voltage-limited charging, even with smart chargers. So the author quoted is perhaps overconcise in his statements. Don't sell the smart chargers too short, Larry! ;-) Chuck ----== Posted via Newsfeeds.Com - Unlimited-Unrestricted-Secure Usenet News==---- http://www.newsfeeds.com The #1 Newsgroup Service in the World! 120,000+ Newsgroups ----= East and West-Coast Server Farms - Total Privacy via Encryption =---- |
#7
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
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#8
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
"roger lothoz" wrote in
: Because all of us would not have enough time in our life to experiment all brands of batteries available on the market place. I would suggest to express individual experiences. Would it be a good idea? AS there is really no difference in the CHEMISTRY of the lead-acid battery, does it really make any difference who makes the same ol' technology we've always used? I think not. Sales hype and outrageous pricing doesn't change chemistry, much....not that much. |
#9
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
"Larry" wrote in message ... "roger lothoz" wrote in : Because all of us would not have enough time in our life to experiment all brands of batteries available on the market place. I would suggest to express individual experiences. Would it be a good idea? AS there is really no difference in the CHEMISTRY of the lead-acid battery, does it really make any difference who makes the same ol' technology we've always used? I think not. Sales hype and outrageous pricing doesn't change chemistry, much....not that much. I may come to regret the decision, but I have decided that, this spring, Escapade will be outfitted with a Rolls 12MD-375M battery. Should a single cell fail (unlikely), I can replace that cell. With proper maintenance, I can expect a minimum of 10 years service, and as much as 20. It's warrantied for at least 7 years. And its modular construction makes it so much easier for me to install and/or remove for winter lay-up. There's much more to battery construction than just chemistry. Karin |
#10
posted to rec.boats.cruising
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Interesting Lead Acid Battery facts
"KLC Lewis" wrote in
et: There's much more to battery construction than just chemistry. I'll bite......Name them. Besides Lead and water and sulfuric acid, there's plastic and rubber. What did I miss?? Lead-Acid batteries are good for about 300 cycles of no more than 50% discharge of capacity. I sure hope you don't depend on them lasting 20 years. Are you talking about the Series 5000 3-year-warranty? "Failure within 36 months from the date placed in service yields FREE REPLACEMENT, not including freight charges from the factory to the applicable destination. After the first 36 months of service, defective batteries will be adjusted for a period of up to 120 months prorated from the date first in service at prices in effect at time of adjustment." I don't see any 10 year warranty, here. 36 months...same as Interstate for how-many-times as much money? Oh, it also says: "To claim a manufacturing warranty, proof of purchase must be presented, showing the date of purchase and the battery's serial number. The battery must be tested by an Authorized Battery Outlet for actual defect, and upon confirmation of the defect, the warranty will be administered. The Warranty does not cover shipping damage, cracked covers, cracked cases, bulged cases from heat, freezing or explosion, discharged batteries, the use of undersized batteries damaged from electrical equipment. This warranty covers only manufacturing defects. The Company makes no warranty with respect to its batteries other than the warranty stated above. All implied warranties of merchantability and all expressed and implied warranties of any other kind are hereby excluded." Notice how it carefully says it doesn't cover "discharged batteries"? So, if I ship 'em a dead battery, that's not covered under the warranty?? If the battery weren't dead, why would I ship it to them in the first place?? "This warranty covers ONLY manufacturing defects." In other words, it doesn't cover sulphation, refusal to stay charged, reduced AH capacity, or anything related to a 500AH battery that only has 100AH of capacity left next year....That's what it says. Who's the "Authorized Battery Outlet" that going to do the testing for the "actual defect" in, say, Belize or Acapulco, if it croaks while we're cruising? "upon confirmation of the DEFECT, the warranty will be administered." What if I don't find a Rolls "Authorized Battery Outlet" in Belize? What if he refuses to come to the boat for "testing"? What will he charge for that? I doubt, "Hello, Rolls? I'm in Belize and the damned thing won't stay charged until morning! I paid $1250 for this thing 2 years and 10 months ago. Send me another one!", is gonna make it happen. Do you? If you think Rolls is going to send you another $800 battery in 2010 when yours is worn out, you are in for a shock! I must admit, however, the red plastic will look more impressive in the lazerette than the golf cart batteries.....(c; I also wanna know what those bolts that hold the cells together in that acid bath are made out of, inside the pretty case. The ears must be lead. Are the bolts lead, too? Anything else just makes another battery with the ears. Don't they rust solid in a year or two? Anyone have corrosion problems between cells where the plates meet under the bolts? |
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