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jim.isbell September 27th 07 02:54 PM

Potable Water - The Third Way.
 
On Sep 22, 10:39 pm, OldNick wrote:
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum? I figured there
had to be a vacuum, although it was not said. But how do you get it?



Gravity.



Glen Walpert September 27th 07 10:25 PM

Potable Water - The Third Way.
 
On Thu, 27 Sep 2007 13:54:13 -0000, "jim.isbell"
wrote:

On Sep 22, 10:39 pm, OldNick wrote:
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum? I figured there
had to be a vacuum, although it was not said. But how do you get it?



Gravity.


Wishful thinking. Where are you going to get the feedwater containing
no noncondensible gasses in solution? In all real distillation plants
a continuosly operating vacuum pump is required to maintain vacuum and
prevent the condensers from filling with noncondensible gasses. There
is no way you are going to eliminate the vacuum pumps with any kind of
inverted tube arrangement.

For reasonable efficiency real distillation plants are multi-stage,
where the latent heat of condensation from one stage is used to boil
feedwater in the next stage, with up to 5 stages being used in larger
plants (in the days before reverse osmosis made them uneconomical by
comparison). Sucessive stages operate at lower pressures, and
corresponding lower temperatures. The 1100 or so BTU required to boil
one pound of water can thus boil up to 5 pounds of water instead.

You still need enough thermal gradient to get the heat to flow through
all those heat exchangers. By using low thermal differentials between
the hot and cold ends you either reduce capacity to a pittance or
require huge and expensive heat exchangers, in either case not
competitive. TANSTAAFL.


[email protected] September 28th 07 01:36 AM

Potable Water - The Third Way.
 
On Thu, 27 Sep 2007 21:25:39 GMT, Glen Walpert
wrote:

On Thu, 27 Sep 2007 13:54:13 -0000, "jim.isbell"
wrote:

On Sep 22, 10:39 pm, OldNick wrote:
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum? I figured there
had to be a vacuum, although it was not said. But how do you get it?



Gravity.


Wishful thinking. Where are you going to get the feedwater containing
no noncondensible gasses in solution? In all real distillation plants
a continuosly operating vacuum pump is required to maintain vacuum and
prevent the condensers from filling with noncondensible gasses. There
is no way you are going to eliminate the vacuum pumps with any kind of
inverted tube arrangement.

For reasonable efficiency real distillation plants are multi-stage,
where the latent heat of condensation from one stage is used to boil
feedwater in the next stage, with up to 5 stages being used in larger
plants (in the days before reverse osmosis made them uneconomical by
comparison). Sucessive stages operate at lower pressures, and
corresponding lower temperatures. The 1100 or so BTU required to boil
one pound of water can thus boil up to 5 pounds of water instead.

You still need enough thermal gradient to get the heat to flow through
all those heat exchangers. By using low thermal differentials between
the hot and cold ends you either reduce capacity to a pittance or
require huge and expensive heat exchangers, in either case not
competitive. TANSTAAFL.



Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)

N:dlzc D:aol T:com \(dlzc\) September 28th 07 02:06 AM

Potable Water - The Third Way.
 
Dear Glen Walpert:

"Glen Walpert" wrote in message
...
On Thu, 27 Sep 2007 13:54:13 -0000, "jim.isbell"
wrote:

On Sep 22, 10:39 pm, OldNick wrote:
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum?
I figured there had to be a vacuum, although it was
not said. But how do you get it?



Gravity.


Wishful thinking. Where are you going to get the
feedwater containing no noncondensible gasses in
solution? In all real distillation plants a continuosly
operating vacuum pump is required to maintain
vacuum and prevent the condensers from filling with
noncondensible gasses. There is no way you are
going to eliminate the vacuum pumps with any kind of
inverted tube arrangement.


But they don't have to be large, and they don't even have to run
continuously (just frequently). There are also going to be
controls...

You could even run it without a vacuum pump until it shut itself
down, drop and purge the gas bubble, then "forklift" your pipes
back up.

And do it at less than the melting point of plastic (should that
be important).

For reasonable efficiency real distillation plants
are multi-stage, where the latent heat of
condensation from one stage is used to boil
feedwater in the next stage, with up to 5 stages
being used in larger plants (in the days before
reverse osmosis made them uneconomical by
comparison).


Scaling is real problem too...

Sucessive stages operate at lower pressures, and
corresponding lower temperatures. The 1100 or
so BTU required to boil one pound of water can
thus boil up to 5 pounds of water instead.

You still need enough thermal gradient to get the
heat to flow through all those heat exchangers.
By using low thermal differentials between the hot
and cold ends you either reduce capacity to a
pittance or require huge and expensive heat
exchangers, in either case not competitive.
TANSTAAFL.


.... a characteristic article ...
http://www.hcn.org/servlets/hcn.Arti...ticle_id=17136
This was not proposed to be a source of free energy, violate the
second law of thermodynamics, or poke fingers in anyone's eyes.

I think it was something that someone could do fairly cheaply, to
get drinkable water from salt water. In other words "a graduate
or undergraduate college project".

I just wonder if you get any improvement in what is left in the
brine, vs. what also evaporates at the lower temperatures...

David A. Smith



Glen Walpert September 28th 07 03:09 PM

Potable Water - The Third Way.
 
On Thu, 27 Sep 2007 18:06:47 -0700, "N:dlzc D:aol T:com \(dlzc\)"
wrote:

Dear Glen Walpert:

"Glen Walpert" wrote in message
.. .
On Thu, 27 Sep 2007 13:54:13 -0000, "jim.isbell"
wrote:

On Sep 22, 10:39 pm, OldNick wrote:
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum?
I figured there had to be a vacuum, although it was
not said. But how do you get it?


Gravity.


Wishful thinking. Where are you going to get the
feedwater containing no noncondensible gasses in
solution? In all real distillation plants a continuosly
operating vacuum pump is required to maintain
vacuum and prevent the condensers from filling with
noncondensible gasses. There is no way you are
going to eliminate the vacuum pumps with any kind of
inverted tube arrangement.


But they don't have to be large, and they don't even have to run
continuously (just frequently). There are also going to be
controls...


The vacuum pumps need to be sized to the load, and it is not a
foregone conclusion that a larger pump running intermittently would be
more efficient than a smaller one running continuosly. Consider also
that the vacuum pump cannot pump out just the noncondensible gasses,
it must pump out the gas mix in the condenser which will be mostly
water vapor - the pumping rate establishes the percentage
noncondensible gasses in the condenser, amd the optimum rate needs to
be established as part of a distillation plant design.

You could even run it without a vacuum pump until it shut itself
down, drop and purge the gas bubble, then "forklift" your pipes
back up.


Does this use less energy per gallon produced?

And do it at less than the melting point of plastic (should that
be important).

For reasonable efficiency real distillation plants
are multi-stage, where the latent heat of
condensation from one stage is used to boil
feedwater in the next stage, with up to 5 stages
being used in larger plants (in the days before
reverse osmosis made them uneconomical by
comparison).


Scaling is real problem too...


True, but one which can be solved by limiting brine concentration and
with chemical treatment and/or periodic cleaning.

Sucessive stages operate at lower pressures, and
corresponding lower temperatures. The 1100 or
so BTU required to boil one pound of water can
thus boil up to 5 pounds of water instead.

You still need enough thermal gradient to get the
heat to flow through all those heat exchangers.
By using low thermal differentials between the hot
and cold ends you either reduce capacity to a
pittance or require huge and expensive heat
exchangers, in either case not competitive.
TANSTAAFL.


... a characteristic article ...
http://www.hcn.org/servlets/hcn.Arti...ticle_id=17136
This was not proposed to be a source of free energy, violate the
second law of thermodynamics, or poke fingers in anyone's eyes.


As usual with this sort of article there are no meaningful numbers
included, perhaps because a complete design analysis has not been
done.

I think it was something that someone could do fairly cheaply, to
get drinkable water from salt water. In other words "a graduate
or undergraduate college project".


Doing an analysis of this approach would be a good student exercise.
Not much point building one without doing the anylysis first - a
complete engineering analysis including the selection or design of all
heat exchangers, mist eliminators, pumps, piping etc., including both
performance and cost calculations. It is always cheaper to optimize a
pencil and paper or computer model than hardware, especially for
something so well understood as heat transfer and fluid flow.

I just wonder if you get any improvement in what is left in the
brine, vs. what also evaporates at the lower temperatures...

David A. Smith


I doubt if that would be much of a factor. What contaminants would be
in the feedwater which would evaporate less compared to water as
boiling point is reduced by low pressure?

The biggest issue with distillate quality is carryover; a fine mist of
unevaporated water droplets are inevitably produced by boiling
regardless of temperature, and while most of these can be separated
out, some always make it through to the condenser. This is a big
issue where biological contamination exists in the feedwater,
requiring chlorination of the distillate to make it potable. It might
be possible to eliminate this factor by eliminating the boiling of
bulk liquid, and instead evaporating from a thin film of water flowing
over the heat exchanger surfaces, but I doubt if it would be cost
effective. Perhaps it would be another good student exercise.

dlzc September 28th 07 11:45 PM

Potable Water - The Third Way.
 
Dear Glen Walpert:

On Sep 28, 7:09 am, Glen Walpert wrote:
On Thu, 27 Sep 2007 18:06:47 -0700, "N:dlzc D:aol T:com \(dlzc\)"

....
Gravity.


Wishful thinking. Where are you going to get the
feedwater containing no noncondensible gasses in
solution? In all real distillation plants a continuosly
operating vacuum pump is required to maintain
vacuum and prevent the condensers from filling with
noncondensible gasses. There is no way you are
going to eliminate the vacuum pumps with any kind of
inverted tube arrangement.


But they don't have to be large, and they don't
even have to run continuously (just frequently).
There are also going to be controls...


The vacuum pumps need to be sized to the load,
and it is not a foregone conclusion that a larger
pump running intermittently would be more efficient
than a smaller one running continuosly. Consider
also that the vacuum pump cannot pump out just
the noncondensible gasses, it must pump out the
gas mix in the condenser which will be mostly
water vapor -


So you can get some condensate here, but it will likely have "vacuum
pump oil" in it...

the pumping rate establishes the percentage
noncondensible gasses in the condenser, amd
the optimum rate needs to be established as part
of a distillation plant design.

You could even run it without a vacuum pump
until it shut itself down, drop and purge the gas
bubble, then "forklift" your pipes back up.


Does this use less energy per gallon produced?


Available on a desert island. Simple block and tackle would do.
Since the (de)compression rate is likely low, and the condensation
production rate is necessarily low, if you were not using animal
power, it could be *more* efficient. But you still have to supply or
waste a good deal of heat.

....
For reasonable efficiency real distillation plants
are multi-stage, where the latent heat of
condensation from one stage is used to boil
feedwater in the next stage, with up to 5 stages
being used in larger plants (in the days before
reverse osmosis made them uneconomical by
comparison).


Scaling is real problem too...


True, but one which can be solved by limiting brine
concentration and with chemical treatment and/or
periodic cleaning.


In the case of the marine vacuum distillation unit, they simply have a
constant flow of brine. Probably need to have a "tube within a tube"
to refresh the fluid near the boiling interface.

Sucessive stages operate at lower pressures, and
corresponding lower temperatures. The 1100 or
so BTU required to boil one pound of water can
thus boil up to 5 pounds of water instead.


You still need enough thermal gradient to get the
heat to flow through all those heat exchangers.
By using low thermal differentials between the hot
and cold ends you either reduce capacity to a
pittance or require huge and expensive heat
exchangers, in either case not competitive.
TANSTAAFL.


... a characteristic article ...

http://www.hcn.org/servlets/hcn.Arti...ticle_id=17136
This was not proposed to be a source of free
energy, violate the second law of thermodynamics,
or poke fingers in anyone's eyes.


As usual with this sort of article there are no
meaningful numbers included, perhaps because
a complete design analysis has not been
done.


More than likely omitted because:
- the reporter's eyes were glazing over, or
- they are working on a patent (since you can probably even patent
cheese now).

I think it was something that someone could do
fairly cheaply, to get drinkable water from salt
water. In other words "a graduate or
undergraduate college project".


Doing an analysis of this approach would be a
good student exercise. Not much point building
one without doing the anylysis first - a complete
engineering analysis including the selection or
design of all heat exchangers, mist eliminators,
pumps, piping etc., including both performance
and cost calculations. It is always cheaper to
optimize a pencil and paper or computer model
than hardware, especially for something so well
understood as heat transfer and fluid flow.

I just wonder if you get any improvement in
what is left in the brine, vs. what also
evaporates at the lower temperatures...


I doubt if that would be much of a factor. What
contaminants would be in the feedwater which
would evaporate less compared to water as
boiling point is reduced by low pressure?


Water does get involved in some azeotropes (some alcohols), so
depression of boiling point would not help there. And
thermodynamically, if one of the things you were trying to remove
became a solid at high vacuum (NaOH maybe?) it might help.

The biggest issue with distillate quality is
carryover; a fine mist of unevaporated water
droplets are inevitably produced by boiling
regardless of temperature, and while most
of these can be separated out, some always
make it through to the condenser. This is a
big issue where biological contamination
exists in the feedwater,


Such as natural brines...

requiring chlorination of the distillate to
make it potable. It might be possible to
eliminate this factor by eliminating the
boiling of bulk liquid, and instead
evaporating from a thin film of water flowing
over the heat exchanger surfaces, but I
doubt if it would be cost effective. Perhaps
it would be another good student exercise.


I wonder if the increased viscosity of droplets at lower temperature
would assist in more efficient removal?

Thanks for the discussion...

David A. Smith


jim.isbell September 29th 07 03:42 PM

Potable Water - The Third Way.
 


Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)



A 32' column of water is a continuous vacuum pump. As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column. The fresh water distills off the top of the
sal****er column then migrates as steam to the other side and distills
in the fresh water side....also creating a vacuum. You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.

In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.














jim[_2_] September 29th 07 04:09 PM

Potable Water - The Third Way.
 


"jim.isbell" wrote:


Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)


A 32' column of water is a continuous vacuum pump. As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column. The fresh water distills off the top of the
sal****er column then migrates as steam to the other side and distills
in the fresh water side....also creating a vacuum. You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.


It works but does it work as well as other methods that are simpler and
easier to implement. Also if you have no fresh water on hand to start
with there is no way to make it work. I can see someone getting a
"Darwin Award" by accidentally spilling all there existing freshwater
supply in a failed attempt to get this contraption going.



In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.


That makes no sense. You are going to have a hard time pumping water out
of the fresh water side any faster than gravity can deliver it. The
salty side OTOH, if you rely only on gravity to feed it, will become a
solid block of salt once you have evaporated enough water from it.

-jim

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Richard Casady September 29th 07 05:44 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 14:42:17 -0000, "jim.isbell"
wrote:



Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)



A 32' column of water is a continuous vacuum pump. As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column. The fresh water distills off the top of the
sal****er column then migrates as steam to the other side and distills
in the fresh water side....also creating a vacuum. You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.

In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.


What you describe is just a still, and a 32 ft inverted U will change
nothing. Solar stills are not new. A tall boiler connected to a very
tall cond

Keith Hughes September 29th 07 06:04 PM

Potable Water - The Third Way.
 


jim wrote:

"jim.isbell" wrote:
Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)

A 32' column of water is a continuous vacuum pump.


This is just plain wrong. As a *unit of measure* 32 feet of water
column equals about 13.9 psi. Meaning, if you pumped a 40' column up to
a 39' height with water, equalized the headspace to atmospheric pressure
(assuming 14.7psia), sealed it, then allowed gravity to *drain* the
water column to a height of 2', the resulting pressure in the headspace
will be about 0.8psia. Now you also have 33' of empty evacuated column.

As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column.


Sorry, this makes no sense. Putting water in does not cause it to "pull
down". Yes, you have supply makeup water to maintain column height lost
to evaporation.

The fresh water distills off the top of the
sal****er column then migrates


Yes, and this "migration" is simple diffusion. *And* you have (in the
example above) 33' of column it has to diffuse through on the seawater
side, and however many feet of column on the freshwater side it has to
traverse prior to condensation. If both columns (fresh and sea) are
referenced to the same height, then the evacuated column height on both
sides will be the same, and that diffusion path will be up to 66'. That
does not happen quickly.

In reality, though, the columns won't be referenced to the same level,
with the freshwater column being referenced (i.e. the bottom is opened
to) the deck height on the boat. So the freshwater column will be, say
8' higher than the seawater column. The diffusion path is still the
same, but the evacuated seawater column would then be 37', with 29' on
the freshwater side.

as steam to the other side and distills
in the fresh water side....also creating a vacuum.


No, this does *not* create a vacuum in the sense you seem to mean. It
maintains an equilibrium pressure by lowering the partial pressure of
water vapor generated by the 'boiling' process on the seawater side.

This relates to the critical rate-limiting feature of the system -
maintaining pressure. When you evaporate, or sublime, water into the
headspace, the pressure in the headspace increases. Condensation on the
other side lowers the pressure, and an equilibrium pressure will
eventually be established. For any given temperature, the evaporation
rate is going to be limited by the partial pressures at the
headspace/water-surface interface. It's a feedback loop, More
evaporation - more water vapor molecules liberated to the headspace -
more pressure in the headspace - slower evaporation until the pressure
is reduced. And to reduce the pressure, those molecules have to diffuse
up to 66'.

You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.


Yes, VERY slowly. You can increase *throughput* by increasing the column
diameters, but how practical is that on a boat?


It works but does it work as well as other methods that are simpler and
easier to implement. Also if you have no fresh water on hand to start
with there is no way to make it work.


Not quite true...you can seal the 'freshwater' column, using only the
column walls for condensation surfaces, until you have sufficient
condensate collected to allow the freshwater column to be opened.

I can see someone getting a
"Darwin Award" by accidentally spilling all there existing freshwater
supply in a failed attempt to get this contraption going.


It doesn't *have* to be that way, BUT.... :-)



In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.


And what's 'practical' for useability, is impractical for functionality.
There are no 'soft tubing' materials I'm aware of that have anything
approaching decent heat absorbance, conduction, or emissivity
properties, so that will be another very significant rate limiter in the
system.


That makes no sense. You are going to have a hard time pumping water out
of the fresh water side any faster than gravity can deliver it.


You actually *can't* pump faster than gravity, unless you want to suck
seawater up the column on the other side.

The
salty side OTOH, if you rely only on gravity to feed it, will become a
solid block of salt once you have evaporated enough water from it.


Doubtful that you'd ever get a solid chunk of salt (and short of having
a bypass circulation loop - cooling the column and further reducing
efficiency - I don't see how a pump could even help the situation), but
of course as the salinity increases, the boiling point increases, and at
some point the process will just stall. The heat input won't be
sufficient to boil the brine solution. Then you have to stop, drain,
clean, and start over. How quickly this happens will depend on column
heights and diameters, but it'll happen at some point. Just another
rate-limiting feature.

All these rate limiters are natures way of saying that there is no
thermodynamic free lunch. A low energy input system will have a low
output (in terms of whatever work you want the system to do).

Keith Hughes


Richard Casady September 29th 07 06:35 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 14:42:17 -0000, "jim.isbell"
wrote:



Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)



A 32' column of water is a continuous vacuum pump. As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column. The fresh water distills off the top of the
sal****er column then migrates as steam to the other side and distills
in the fresh water side....also creating a vacuum. You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.

In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.


What you describe is just a still, and a 32 ft inverted U will change
nothing. Solar stills are not new. A very tall boiler connected to a
very tall condenser is all you describe.

Why don't you build one and let us know just how it is superior to any
other solar still, especially ones without all the windage and
topweight.

By the way, it takes about 1100 BTU's evaporate a pound of water, and
this does not vary with pressure. How much sunlight is your still
going to intercept? Sunlight is a maximum of about 1400 watts per sq
meter, or, according to the 'calculator that takes no prisoners', the
HP48, about one eighth of a BTU /sq ft/sec.
Something like half a pound of water evaporated per hour, per sq ft.
This assumes that the collector is squarely aimed at the sun, at all
times. What you want is the largest possible shadow. A rectangle 1 in
by 32 ft is about 2,66 sq ft., by the way. A tube is not a very
efficient shape for a solar collector, of course, but it simplifies
aiming it, since a vertical cylinder looks the same from every
horizontal angle. Your vertical tube will face the sun nice and square
at sunrise and sunset.

Casady

Brian Whatcott September 29th 07 07:57 PM

Potable Water - The Third Way.
 

Hmmmm...here's somebody at least taking a shot at analyzing the
system. I interpose one or two little comments....


On Sat, 29 Sep 2007 10:04:43 -0700, Keith Hughes
wrote:

"jim.isbell" wrote:

/.../

This is just plain wrong. As a *unit of measure* 32 feet of water
column equals about 13.9 psi. Meaning, if you pumped a 40' column up to
a 39' height with water, equalized the headspace to atmospheric pressure
(assuming 14.7psia), sealed it, then allowed gravity to *drain* the
water column to a height of 2', the resulting pressure in the headspace
will be about 0.8psia. Now you also have 33' of empty evacuated column.



My, my: "it's just plain wrong": he said a column of 32 ft, and
you correct him - it's 33 ft. What a loser he must be! :-)
But then, you are neglecting to account for the density of SALT water!

Not strictly relevant, but interesting to me at least:
Joseph Priestley kept a water barometer at his house in Birmingham
(before the mob drove him out for his revolutionary sympathies).
Guess how high he had to climb to read the water level?


The fresh water distills off the top of the
sal****er column then migrates


Yes, and this "migration" is simple diffusion. *And* you have (in the
example above) 33' of column it has to diffuse through on the seawater
side, and however many feet of column on the freshwater side it has to
traverse prior to condensation. If both columns (fresh and sea) are
referenced to the same height, then the evacuated column height on both
sides will be the same, and that diffusion path will be up to 66'. That
does not happen quickly.



Uh? Diffusion of water molecules in low pressure air through 66 feet?

Let's say 14 ft, 20 feet even. Now what would the speed be?
Hmmmm. Let's see. Would that speed be over 500 meters/second?

That's so slow, the time it might take to travel 20 feet,
say 6 meters at 500 m/s might be 12 milliseconds?

Here's a review of the thermo equation.
Just plant the temperature of interest (20 degC say) and the molecular
weght of a water molecule (Hint: its lighter than the average molecule
that makes up air) in the following calculator

http://hyperphysics.phy-astr.gsu.edu...kintem.html#c4


In reality, though, the columns won't be referenced to the same level,
with the freshwater column being referenced (i.e. the bottom is opened
to) the deck height on the boat. So the freshwater column will be, say
8' higher than the seawater column. The diffusion path is still the
same, but the evacuated seawater column would then be 37', with 29' on
the freshwater side.



Hmmmm...a freeboard of eight feet? Some boat! More boat than I've got,
certainly.


This relates to the critical rate-limiting feature of the system -
maintaining pressure. When you evaporate, or sublime, water into the
headspace, the pressure in the headspace increases.


The word is "BOIL", not evaporate, not sublime. If it is not
quickly condensed returning latent heat, the partial pressure rises
quickly sure enough. Better condense it then! I imagine a central
cold finger of cool salt water in the fresh column might be effective?
(That would however take a hand pump capable of supplying a flow
at 15 psi plus. Like a bicycle pump, or better? )


Condensation on the
other side lowers the pressure, and an equilibrium pressure will
eventually be established. For any given temperature, the evaporation
rate is going to be limited by the partial pressures at the
headspace/water-surface interface. It's a feedback loop, More
evaporation - more water vapor molecules liberated to the headspace -
more pressure in the headspace - slower evaporation until the pressure
is reduced. And to reduce the pressure, those molecules have to diffuse
up to 66'.


There you go again - with your really really slow 66 ft diffusion for
condensed water in the fresh column.....


I can see someone getting a
"Darwin Award" by accidentally spilling all their existing freshwater
supply in a failed attempt to get this contraption going.


It doesn't *have* to be that way, BUT.... :-)


Keith Hughes



In my experience, the people who talk most about Darwin awards
are completely foggy about how Darwinian selection operates.

"Accidentally spilling all fresh water" , from a "contraption"
Yes, sure. Can you say, "Straw man?"

Brian W

Keith Hughes September 29th 07 08:59 PM

Potable Water - The Third Way.
 
Brian Whatcott wrote:
Hmmmm...here's somebody at least taking a shot at analyzing the
system. I interpose one or two little comments....


On Sat, 29 Sep 2007 10:04:43 -0700, Keith Hughes
wrote:

"jim.isbell" wrote:

/.../

This is just plain wrong. As a *unit of measure* 32 feet of water
column equals about 13.9 psi. Meaning, if you pumped a 40' column up to
a 39' height with water, equalized the headspace to atmospheric pressure
(assuming 14.7psia), sealed it, then allowed gravity to *drain* the
water column to a height of 2', the resulting pressure in the headspace
will be about 0.8psia. Now you also have 33' of empty evacuated column.



My, my: "it's just plain wrong": he said a column of 32 ft,


Uhmmm, no, he said a "32' column of water". Can you see the difference?

and
you correct him - it's 33 ft.


You clearly need to re-read the paragraph whose point you're mangling.
The 33' you quote is not a correction to the OP, but a point for further
discussion (which you misunderstand later on).

What a loser he must be! :-)
But then, you are neglecting to account for the density of SALT water!


And "about 0.8psia" makes what claim of precision?

snip

Yes, and this "migration" is simple diffusion.


snip


Uh? Diffusion of water molecules in low pressure air through 66 feet?

Let's say 14 ft, 20 feet even. Now what would the speed be?
Hmmmm. Let's see. Would that speed be over 500 meters/second?

That's so slow, the time it might take to travel 20 feet,
say 6 meters at 500 m/s might be 12 milliseconds?

Here's a review of the thermo equation.
Just plant the temperature of interest (20 degC say) and the molecular
weght of a water molecule (Hint: its lighter than the average molecule
that makes up air) in the following calculator

http://hyperphysics.phy-astr.gsu.edu...kintem.html#c4


Gee, I didn't know you were using 'smart' molecules that travel *only*
in the direction you want them too. And they don't bump into each other
in the process. Wow, that's really neat, how did you accomplish that?
Barring that, of what value, or relevance is the above?

Here's a little thought experiment for you: Given the random
distribution of molecular velocities and directions (look at the
Boltzman and Maxwell discussion on the site you referenced, for
example), you can pick a point say 1 foot above the water surface, in
the center of the tube (NOTE: 1 foot is an Example). From this point,
every molecule has *almost* the same chance of going up, down, north,
south, east, west, or any direction in between right? If you say "no",
look at your own reference again. Given this, tell me again how the
molecular speed is *proportional* to the diffusion rate? (Hint: It's not)


In reality, though, the columns won't be referenced to the same level,
with the freshwater column being referenced (i.e. the bottom is opened
to) the deck height on the boat. So the freshwater column will be, say
8' higher than the seawater column. The diffusion path is still the
same, but the evacuated seawater column would then be 37', with 29' on
the freshwater side.



Hmmmm...a freeboard of eight feet? Some boat! More boat than I've got,
certainly.


Mayhap a definition of "example" could be of help to you?



This relates to the critical rate-limiting feature of the system -
maintaining pressure. When you evaporate, or sublime, water into the
headspace, the pressure in the headspace increases.


The word is "BOIL",


*If* the temp is high enough, yes. This system, in the currently
discussed configuration, is most likely to oscillate between boiling and
evaporation. I mentioned sublimation since posters continually reference
"ice to steam" in this context, and the concept is the same.

not evaporate, not sublime. If it is not
quickly condensed returning latent heat, the partial pressure rises
quickly sure enough.


So if you condense it quickly enough, then there is no pressure rise?
Right. Look at your own reference above then, and tell me where the
energy went between boiling and condensing. That was a GAS law you were
citing no?

And "quickly condensed returning latent heat" has a name; refluxing.
Refluxing = no distilled water. Get the drift?

Better condense it then! I imagine a central
cold finger of cool salt water in the fresh column might be effective?
(That would however take a hand pump capable of supplying a flow
at 15 psi plus. Like a bicycle pump, or better? )


Condensation on the
other side lowers the pressure, and an equilibrium pressure will
eventually be established. For any given temperature, the evaporation
rate is going to be limited by the partial pressures at the
headspace/water-surface interface. It's a feedback loop, More
evaporation - more water vapor molecules liberated to the headspace -
more pressure in the headspace - slower evaporation until the pressure
is reduced. And to reduce the pressure, those molecules have to diffuse
up to 66'.


There you go again - with your really really slow 66 ft diffusion for
condensed water in the fresh column.....


There you go again with your absurd assumption that all the kinetic
energy of the gas translates into motion in one direction only...


I can see someone getting a
"Darwin Award" by accidentally spilling all their existing freshwater
supply in a failed attempt to get this contraption going.


It doesn't *have* to be that way, BUT.... :-)


Keith Hughes



In my experience, the people who talk most about Darwin awards
are completely foggy about how Darwinian selection operates.


Yeah, that's likely. I don't think we ever talked about Darwin when I
was getting my biology degree...

"Accidentally spilling all fresh water" , from a "contraption"
Yes, sure. Can you say, "Straw man?"


You also seem to need a refresher on how email/newsgroup postings are
structured. A casual glance would show that the quote you're mocking
was not mine.

Keith Hughes



Richard Casady September 29th 07 09:40 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 13:57:27 -0500, Brian Whatcott
wrote:

(That would however take a hand pump capable of supplying a flow
at 15 psi plus. Like a bicycle pump, or better? )


Grease guns are, some of them, capable of at least. hundreds of psi.
I happen to own a 0-5000 psi gauge. Bought it to check tractor
hydralic systems. I forget just what a grease gun pumped it up to, but
it was a lot.
There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady

Brian Whatcott September 29th 07 10:54 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 20:40:57 GMT, (Richard
Casady) wrote:

(That would however take a hand pump capable of supplying a flow
at 15 psi plus. Like a bicycle pump, or better? )


Grease guns are, some of them, capable of at least. hundreds of psi.
I happen to own a 0-5000 psi gauge. Bought it to check tractor
hydraulic systems. I forget just what a grease gun pumped it up to, but
it was a lot.
There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady



How interesting! Sure enough, a grease gun can usually put up 1000's
of psi. and a low volume RO with such a hand pump seems like a
reasonably economic proposition. Wonder how much they cost.
Must take a look!

Brian W

Brian Whatcott September 29th 07 11:02 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 12:59:39 -0700, Keith Hughes
wrote:


My, my: "it's just plain wrong": he said a column of 32 ft,


Uhmmm, no, he said a "32' column of water". Can you see the difference?


Hmmm..Priestley certainly could. His water barometer had a water
column round 32 or 33 ft high.
How 'bout that! :-)

Gee, I didn't know you were using 'smart' molecules that travel *only*
in the direction you want them too.

.....
Keith Hughes



Ho, hum: if half of them go in the wrong direction
until their first collision, it must take them a really, really,
REALLY long time to diffuse through the water vapor/rarified air mix!

Brian W

N:dlzc D:aol T:com \(dlzc\) September 29th 07 11:30 PM

Potable Water - The Third Way.
 
Dear Richard Casady:

"Richard Casady" wrote in message
.. .
On Sat, 29 Sep 2007 13:57:27 -0500, Brian Whatcott
wrote:

(That would however take a hand pump capable
of supplying a flow at 15 psi plus. Like a bicycle
pump, or better? )


Grease guns are, some of them, capable of at
least. hundreds of psi. I happen to own a 0-5000
psi gauge. Bought it to check tractor hydralic
systems. I forget just what a grease gun pumped
it up to, but it was a lot.


But it was a *very* low flow rate. Brian is talking about "a
few" gallons per minute, to use cooler salt water in a tube on
the "fresh water" side to help carry off waste heat. And it is
going upwards a few tens of feet (then back down), perhaps
starting at atmospheric pressure. It would be hard work,
especially it it had to be kept up for an hour!

There is a reverse osmosis watermaker
intended for liferaft use, with a hand pump, and
RO takes hundreds of psi. That is what you want,
if you actually need high pressure.


I figure you probably can buy a small hand-held "single-shot"
pocket RO unit for just such a purpose...

David A. Smith



Richard Casady September 29th 07 11:39 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 12:59:39 -0700, Keith Hughes
wrote:

Gee, I didn't know you were using 'smart' molecules that travel *only*
in the direction you want them too. And they don't bump into each other
in the process. Wow, that's really neat, how did you accomplish that?


I noticed that.

Isn't the speed of sound, whatever it is, what it is because it _is _
the molecular speed? They both vary with temperature but not pressure.

Casady

Brian Whatcott September 29th 07 11:43 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 20:40:57 GMT, (Richard
Casady) wrote:


There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady



I looked up an example
The Katadyn Survivor 35 hand pumped was formerly
called the PUR Survivor 35 RO.
At 30 strokes/minute for 1.2 gall/hr - it costs $1500.

Not cheap.
Volume production ought to bring that down a bit?

Brian W

Keith Hughes September 29th 07 11:51 PM

Potable Water - The Third Way.
 
Brian Whatcott wrote:
On Sat, 29 Sep 2007 12:59:39 -0700, Keith Hughes
wrote:


My, my: "it's just plain wrong": he said a column of 32 ft,

Uhmmm, no, he said a "32' column of water". Can you see the difference?


Hmmm..Priestley certainly could. His water barometer had a water
column round 32 or 33 ft high.
How 'bout that! :-)


Quite true, which probably engenders the confusion. However, the
barometer *starts* with an evacuated column. That's how the atmospheric
pressure can push the water 32' up the column - you have 14.7 PSIA to
work with to lift the water. Same for a mercury barometer, or a McCleod
gauge, etc.

Different story than using the water column to *generate* the vacuum.


Gee, I didn't know you were using 'smart' molecules that travel *only*
in the direction you want them too.

....
Keith Hughes



Ho, hum: if half of them go in the wrong direction
until their first collision, it must take them a really, really,
REALLY long time to diffuse through the water vapor/rarified air mix!


Half? More likely 99.99999++% of them will not be traveling parallel to
the axis of the column. Half of those that *are*, are going in the wrong
direction.

How difficult this type of mass transport actually is can be seen by
looking at flow rates for water vapor from lyophilizer chambers to the
condensers (yes, I have done this a lot). Putting a 90° bend in the tube
connecting the chamber (where the ice sits on heated shelves) and the
condenser roughly (very roughly, given the variability of other design
factors) cuts the flow rate in half. That's in a 48" ID tube too! And
pulling vacuum through the condenser to maintain 50-100 microbar
pressure - i.e. maintaining a significant delta-P from chamber to
condenser. And with condenser coils maintained at -65°C.

It may seem counterintuitive, but the molecular motion you referenced
just *causes* the pressure, while providing little impetus for mass
transfer from point A to point B. And once the pressure reaches
equilibrium throughout the system, you have to rely virtually entirely
on diffusion, which is much, much slower.

Keith Hughes

Vic Smith September 30th 07 02:38 AM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 17:43:02 -0500, Brian Whatcott
wrote:

On Sat, 29 Sep 2007 20:40:57 GMT, (Richard
Casady) wrote:


There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady



I looked up an example
The Katadyn Survivor 35 hand pumped was formerly
called the PUR Survivor 35 RO.
At 30 strokes/minute for 1.2 gall/hr - it costs $1500.

Calorie expenditure by the survivor(s) could be a problem here.
The strokes for this RO unit can probably be performed by devising a
simple hydraulic pump to move gears, cams, and levers.
The pump cylinder itself would probably need an inverted U tube with
legs perhaps 32' or 33' long.
An initial vacuum might be applied to the top of the U-tube by using a
fitting that can be connected to the PUR Survivor 35 RO.
Once the water starts flowing through the vane at one end of the U
tube, and the vane shaft is turning the gears, cams and levers will be
clacking way, running that PUR unit on auto, good as gold.
After that it's all gravy until you have to change the membrane.
In the meantime you can spend your time fishing until rescued.

--Vic

Keith Hughes September 30th 07 03:44 AM

Potable Water - The Third Way.
 
Vic Smith wrote:
On Sat, 29 Sep 2007 17:43:02 -0500, Brian Whatcott
wrote:

On Sat, 29 Sep 2007 20:40:57 GMT, (Richard
Casady) wrote:


There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady


I looked up an example
The Katadyn Survivor 35 hand pumped was formerly
called the PUR Survivor 35 RO.
At 30 strokes/minute for 1.2 gall/hr - it costs $1500.

Calorie expenditure by the survivor(s) could be a problem here.


Oh yeah, right. Now you want to survive also. Geez, what next? :-)

The strokes for this RO unit can probably be performed by devising a
simple hydraulic pump to move gears, cams, and levers.
The pump cylinder itself would probably need an inverted U tube with
legs perhaps 32' or 33' long.
An initial vacuum might be applied to the top of the U-tube by using a
fitting that can be connected to the PUR Survivor 35 RO.
Once the water starts flowing through the vane at one end of the U
tube, and the vane shaft is turning the gears, cams and levers will be
clacking way, running that PUR unit on auto, good as gold.
After that it's all gravy until you have to change the membrane.
In the meantime you can spend your time fishing until rescued.


Sounds like perpetual motion to me, but I'm having a hard time
envisioning what you're describing above.

Keith Hughes

Richard Casady September 30th 07 07:07 AM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 19:44:35 -0700, Keith Hughes
wrote:

Sounds like perpetual motion to me, but I'm having a hard time
envisioning what you're describing above.


Of course you are, since it is basically nonsense. No mention of where
the energy comes from.

Casady

Richard Casady September 30th 07 07:19 AM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 20:38:17 -0500, Vic Smith
wrote:

The strokes for this RO unit can probably be performed by devising a
simple hydraulic pump to move gears, cams, and levers.


It comes with a simple hydraulic pump. I fail to see where adding
complicated machinery, with no power source whatever, will be of any
benefit.

Casady

N:dlzc D:aol T:com \(dlzc\) September 30th 07 06:14 PM

Potable Water - The Third Way.
 
Dear Richard Casady:

"Richard Casady" wrote in message
...
On Sat, 29 Sep 2007 19:44:35 -0700, Keith Hughes
wrote:

Sounds like perpetual motion to me, but I'm
having a hard time envisioning what you're
describing above.


Of course you are, since it is basically nonsense.
No mention of where the energy comes from.


Links were provided. "waste heat" (from what process?) and / or
"solar heat" have been cited so far. All the vacuum does is move
boiling temperature closer to ambient. Making more common
materials suitable for this application.

David A. Smith



Keith Hughes September 30th 07 07:38 PM

Potable Water - The Third Way.
 
N:dlzc D:aol T:com (dlzc) wrote:
Dear Richard Casady:

"Richard Casady" wrote in message
...
On Sat, 29 Sep 2007 19:44:35 -0700, Keith Hughes
wrote:

Sounds like perpetual motion to me, but I'm
having a hard time envisioning what you're
describing above.

Of course you are, since it is basically nonsense.
No mention of where the energy comes from.


Links were provided. "waste heat" (from what process?) and / or
"solar heat" have been cited so far. All the vacuum does is move
boiling temperature closer to ambient. Making more common
materials suitable for this application.

David A. Smith


Sorry David, I think you lost track of the posting train here. Richard
was responding to *my* response to the following post from "Vic":

"Calorie expenditure by the survivor(s) could be a problem here.
The strokes for this RO unit can probably be performed by devising a
simple hydraulic pump to move gears, cams, and levers.
The pump cylinder itself would probably need an inverted U tube with
legs perhaps 32' or 33' long.
An initial vacuum might be applied to the top of the U-tube by using a
fitting that can be connected to the PUR Survivor 35 RO.
Once the water starts flowing through the vane at one end of the U
tube, and the vane shaft is turning the gears, cams and levers will be
clacking way, running that PUR unit on auto, good as gold.
After that it's all gravy until you have to change the membrane.
In the meantime you can spend your time fishing until rescued."

Which appears to be a reference to a perpetual motion machine with no
energy source. Nothing whatsoever to do with the vacuum distillation
discussion.

Keith Hughes




jim.isbell September 30th 07 08:13 PM

Potable Water - The Third Way.
 
I give up. My Masters degree in Physics is of no value here. My
Bachelors degree in Math is of no value here. My 20 years with the
university (retired) means nothing. Someone with an opinion (however
false) instead of facts of physical science, seems to be more able to
swing the belief of the uninformed.

I will try to explain it again.

The vacuum will hold the column of water in the tube.

Dont believe it?
Test this statement, take a simple soda straw stick in in a glass of
water put your finger over the end and lift it out. The 8" column of
water stays in the straw because of the vacuum in the top of the
straw. Now remove your finger and the water drops out. So, it
doesn't TAKE a 32' column of water, but that is the tallest column of
water that will be suspended, a simple law of physics.

Thats why a lift pump like the old rocker handle pitcher pumps have to
be replaced with either submerged or Jet pumps in deeper wells. A
lesser column WILL work however. At the top is a vacuum. If its 32
feet, thats the greatest vacuum you can create. There is salt water
on one side and fresh water on the other. The salt water will boil
earlier because of the salt content.

Now test that statement.
Put a pot on the stove and then before it comes to a boil add salt.
Voila, it begins to boil.

The fresh water column is sealed at the bottom and fresh water, as it
builds a higher column, can be drawn off WITH A PUMP. You cannot open
the bottom of the tube to get the water out or you will break the
vacuum. As you draw fresh water off WITH THE PUMP you will draw salt
water into the bottom of the other end (which is under the surface of
the salt water the boat is floating in) to replace the salt water that
has been boiled off. Obviously you will have to be careful that you
don't pull off enough fresh water to cause the sal****er column to
overflow into and contaminate the fresh water column. Also, I make no
representation as to the efficiency of such a system, only that it
WILL work.

Now, I have nothing more to say on the subject as I don't have the
time to waste. I didn't realize I would have to go into such
miniscule detail. I have been casting my pearls before swine and I
dont have the time for that. If someone with an appropriate education
and who has done the above experiments as I outlined, would like to
contact me off list I would be willing to discuss it. BUT...if you
are supposing, without knowledge, using feelings for facts, DONT
bother me.

On Sep 29, 12:04 pm, Keith Hughes wrote:
jim wrote:

"jim.isbell" wrote:
Ah well, another great idea skuppered by dat old devil science :-)


Bruce in Bangkok
(brucepaigeATgmailDOTcom)
A 32' column of water is a continuous vacuum pump.


This is just plain wrong. As a *unit of measure* 32 feet of water
column equals about 13.9 psi. Meaning, if you pumped a 40' column up to
a 39' height with water, equalized the headspace to atmospheric pressure
(assuming 14.7psia), sealed it, then allowed gravity to *drain* the
water column to a height of 2', the resulting pressure in the headspace
will be about 0.8psia. Now you also have 33' of empty evacuated column.

As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column.


Sorry, this makes no sense. Putting water in does not cause it to "pull
down". Yes, you have supply makeup water to maintain column height lost
to evaporation.

The fresh water distills off the top of the
sal****er column then migrates


Yes, and this "migration" is simple diffusion. *And* you have (in the
example above) 33' of column it has to diffuse through on the seawater
side, and however many feet of column on the freshwater side it has to
traverse prior to condensation. If both columns (fresh and sea) are
referenced to the same height, then the evacuated column height on both
sides will be the same, and that diffusion path will be up to 66'. That
does not happen quickly.

In reality, though, the columns won't be referenced to the same level,
with the freshwater column being referenced (i.e. the bottom is opened
to) the deck height on the boat. So the freshwater column will be, say
8' higher than the seawater column. The diffusion path is still the
same, but the evacuated seawater column would then be 37', with 29' on
the freshwater side.

as steam to the other side and distills
in the fresh water side....also creating a vacuum.


No, this does *not* create a vacuum in the sense you seem to mean. It
maintains an equilibrium pressure by lowering the partial pressure of
water vapor generated by the 'boiling' process on the seawater side.

This relates to the critical rate-limiting feature of the system -
maintaining pressure. When you evaporate, or sublime, water into the
headspace, the pressure in the headspace increases. Condensation on the
other side lowers the pressure, and an equilibrium pressure will
eventually be established. For any given temperature, the evaporation
rate is going to be limited by the partial pressures at the
headspace/water-surface interface. It's a feedback loop, More
evaporation - more water vapor molecules liberated to the headspace -
more pressure in the headspace - slower evaporation until the pressure
is reduced. And to reduce the pressure, those molecules have to diffuse
up to 66'.

You draw off the
fresh water on one side and pump salt water into the other side. The
salt water side is painted black to absorb sun heat and the fresh
water side is painted white to reflect the suns heat. You only need a
few degrees difference for distillation and the vacuum creates the
boiling at low temperatures...even ice will change state to steam in a
vacuum. The idea works.


Yes, VERY slowly. You can increase *throughput* by increasing the column
diameters, but how practical is that on a boat?



It works but does it work as well as other methods that are simpler and
easier to implement. Also if you have no fresh water on hand to start
with there is no way to make it work.


Not quite true...you can seal the 'freshwater' column, using only the
column walls for condensation surfaces, until you have sufficient
condensate collected to allow the freshwater column to be opened.

I can see someone getting a
"Darwin Award" by accidentally spilling all there existing freshwater
supply in a failed attempt to get this contraption going.


It doesn't *have* to be that way, BUT.... :-)



In a practical sense, I would use soft tubing for the sides and a
solid "U" shaped piece of copper tubing for the top center with a ring
soldered to it so it could be hoisted up the mast of a sailboat. It
would take a 30 to 40 foot mast to do the job. The bottom end of the
salt water tube could go to a through hull for a continuous supply of
salt water and the bottom end of the fresh water tube could go to a
small pump to remove the water without breaking the vacuum.


And what's 'practical' for useability, is impractical for functionality.
There are no 'soft tubing' materials I'm aware of that have anything
approaching decent heat absorbance, conduction, or emissivity
properties, so that will be another very significant rate limiter in the
system.



That makes no sense. You are going to have a hard time pumping water out
of the fresh water side any faster than gravity can deliver it.


You actually *can't* pump faster than gravity, unless you want to suck
seawater up the column on the other side.

The
salty side OTOH, if you rely only on gravity to feed it, will become a
solid block of salt once you have evaporated enough water from it.


Doubtful that you'd ever get a solid chunk of salt (and short of having
a bypass circulation loop - cooling the column and further reducing
efficiency - I don't see how a pump could even help the situation), but
of course as the salinity increases, the boiling point increases, and at
some point the process will just stall. The heat input won't be
sufficient to boil the brine solution. Then you have to stop, drain,
clean, and start over. How quickly this happens will depend on column
heights and diameters, but it'll happen at some point. Just another
rate-limiting feature.

All these rate limiters are natures way of saying that there is no
thermodynamic free lunch. A low energy input system will have a low
output (in terms of whatever work you want the system to do).

Keith Hughes




David Scheidt September 30th 07 08:35 PM

Potable Water - The Third Way.
 
In rec.boats.cruising jim.isbell wrote:
:I give up. My Masters degree in Physics is of no value here. My

Not if you think salt water has a lower boiling point than fresh, no.

N:dlzc D:aol T:com \(dlzc\) September 30th 07 10:03 PM

Potable Water - The Third Way.
 
Dear jim.isbell:

"jim.isbell" wrote in message
ups.com...
I give up. My Masters degree in Physics is of
no value here. My Bachelors degree in Math
is of no value here. My 20 years with the
university (retired) means nothing. Someone
with an opinion (however false) instead of facts
of physical science, seems to be more able to
swing the belief of the uninformed.


Someone with this much experience must know that the ignorant
will always trample the carpet of wisdom. Why do you waste your
time responding to them?

The entire comedy is misinterpretation of wording, and argument
about strawmen. Relax and have what is left of a weekend. For
they (in this case) are as right as you are... just about
different things.

David A. Smith



Keith Hughes September 30th 07 10:16 PM

Potable Water - The Third Way.
 
Wow, Pearls! Let this swine take a look and see if he can root them out...

jim.isbell wrote:
I give up. My Masters degree in Physics is of no value here. My
Bachelors degree in Math is of no value here. My 20 years with the
university (retired) means nothing. Someone with an opinion (however
false) instead of facts of physical science, seems to be more able to
swing the belief of the uninformed.


I stand (sit actually) abashed in the light of your professed achievements.


I will try to explain it again.

The vacuum will hold the column of water in the tube.


Pearl #1? Hmmm, no. No one claimed otherwise. continued rooting sound

snip irrelevancies related to above statement

Thats why a lift pump like the old rocker handle pitcher pumps have to
be replaced with either submerged or Jet pumps in deeper wells. A
lesser column WILL work however. At the top is a vacuum. If its 32
feet, thats the greatest vacuum you can create. There is salt water
on one side and fresh water on the other. The salt water will boil
earlier because of the salt content.


Pearl #1? Hmmm, alas no. Physics relating ionic strength and boiling
point of water must have changed since your education. continued
rooting sound

Now test that statement.
Put a pot on the stove and then before it comes to a boil add salt.
Voila, it begins to boil.


Pearl #1? Hmmm, no dice here either. It's called *nucleation*. Ever
notice the water *stops* boiling as soon as the salt is fully dissolved?
And doesn't boil again until the new, higher, boiling point is
reached? Try it. continued rooting sound


The fresh water column is sealed at the bottom and fresh water, as it
builds a higher column, can be drawn off WITH A PUMP. You cannot open
the bottom of the tube to get the water out or you will break the
vacuum.


Pearl #1? Hmmm, not yet. Of course you can pull water from the BOTTOM
of the freshwater column - if its end is below the freshwater reservoir
level. Just like the seawater side is. Elevate the freshwater
reservoir, decant to maintain column height. No pump needed. How hard
was that? continued rooting sound

snip


Also, I make no
representation as to the efficiency of such a system, only that it
WILL work.


Pearl #1? Hmmm, well, maybe a tiny, dull one - well, maybe not, no one
said it wouldn't work. And if you think the 'perpetual motion'
reference was to this system, then learn to read. That post was about
*RO* and using this system as a hydraulic pump mechanism. continued
rooting sound

Now, I have nothing more to say on the subject as I don't have the
time to waste. I didn't realize I would have to go into such
miniscule detail. I have been casting my pearls before swine and I
dont have the time for that. If someone with an appropriate education
and who has done the above experiments as I outlined, would like to
contact me off list I would be willing to discuss it. BUT...if you
are supposing, without knowledge, using feelings for facts, DONT
bother me.


OK Mr. Oyster. Oh, and by-the-by, *you* choose to be bothered or not, we
don't do that for you. Have fun in bivalvia...

Keith Hughes

[email protected] September 30th 07 10:54 PM

Potable Water - The Third Way.
 
On Sep 30, 9:13 am, "jim.isbell" wrote:
... The salt water will boil
earlier because of the salt content. ...


http://en.wikipedia.org/wiki/Boiling-point_elevation

-- Tom.


Vic Smith September 30th 07 11:25 PM

Potable Water - The Third Way.
 
On Sat, 29 Sep 2007 19:44:35 -0700, Keith Hughes
wrote:

Vic Smith wrote:
On Sat, 29 Sep 2007 17:43:02 -0500, Brian Whatcott
wrote:

On Sat, 29 Sep 2007 20:40:57 GMT, (Richard
Casady) wrote:


There is a reverse osmosis watermaker intended for liferaft use, with
a hand pump, and RO takes hundreds of psi. That is what you want, if
you actually need high pressure.

Casady

I looked up an example
The Katadyn Survivor 35 hand pumped was formerly
called the PUR Survivor 35 RO.
At 30 strokes/minute for 1.2 gall/hr - it costs $1500.

Calorie expenditure by the survivor(s) could be a problem here.


Oh yeah, right. Now you want to survive also. Geez, what next? :-)

The strokes for this RO unit can probably be performed by devising a
simple hydraulic pump to move gears, cams, and levers.
The pump cylinder itself would probably need an inverted U tube with
legs perhaps 32' or 33' long.
An initial vacuum might be applied to the top of the U-tube by using a
fitting that can be connected to the PUR Survivor 35 RO.
Once the water starts flowing through the vane at one end of the U
tube, and the vane shaft is turning the gears, cams and levers will be
clacking way, running that PUR unit on auto, good as gold.
After that it's all gravy until you have to change the membrane.
In the meantime you can spend your time fishing until rescued.


Sounds like perpetual motion to me, but I'm having a hard time
envisioning what you're describing above.

Sorry, it was all said jokingly, but appears to be a poor joke.
I just went in a circle from the perpetual U-tube distiller to that
concept being employed to perpetually pump a purchased RO unit.
I never intended to make sense, except maybe to say it's time to go
fishing.

--Vic

Richard Casady October 2nd 07 05:42 PM

Potable Water - The Third Way.
 
On Sat, 22 Sep 2007 17:51:56 -0400, "Wilbur Hubbard"
wrote:

When it gets full you haul it up and empty in
into your tanks. Reverse osmosis without any energy used to get it.
Ain't Wilbur brilliant?

You haul it up without using any energy to do it? Absolutely not/ It
will take a foot pound for each pound for each foot you haul it.
No your basis for perpetual motion will not work. And is the opposite
of brilliant.

Casady

RW Salnick October 2nd 07 05:59 PM

Potable Water - The Third Way.
 
Richard Casady brought forth on stone tablets:
On Sat, 22 Sep 2007 17:51:56 -0400, "Wilbur Hubbard"
wrote:


When it gets full you haul it up and empty in
into your tanks. Reverse osmosis without any energy used to get it.
Ain't Wilbur brilliant?


You haul it up without using any energy to do it? Absolutely not/ It
will take a foot pound for each pound for each foot you haul it.
No your basis for perpetual motion will not work. And is the opposite
of brilliant.

Casady


Well, not quite. The harvested fresh water is actually buoyant in the
sea water. Hauling up the water is energy free. Hauling up the
container and the rope is not, however.

With suitable flotation, the container could be made neutral-buoyant,
and so hauling it up could be free also, Finally, if the rope were HD
polyethylene or something else with about 1.0 density, the rope could be
free to hoist too. It would be necessary to attach a weight greater
than the weight of water to be harvested to the container in order to
get it to sink. This weight would then be disconnected/abandoned before
hoisting the recovered water. From an energy standpoint, the investment
would be that necessary to cover the friction in the hauling apparatus,
and the the invested energy content of the abandoned weight (steel:
high, concrete: medium, rock: free).

Venting the container to the surface would be impractical. Evacuate it
instead.

With Wilbur, one must be careful to not discard the wheat with the chaff...

bob
s/v Eolian
Seattle


[email protected] October 3rd 07 01:39 AM

Potable Water - The Third Way.
 
On Tue, 02 Oct 2007 09:59:46 -0700, RW Salnick
wrote:

Richard Casady brought forth on stone tablets:
On Sat, 22 Sep 2007 17:51:56 -0400, "Wilbur Hubbard"
wrote:


When it gets full you haul it up and empty in
into your tanks. Reverse osmosis without any energy used to get it.
Ain't Wilbur brilliant?


You haul it up without using any energy to do it? Absolutely not/ It
will take a foot pound for each pound for each foot you haul it.
No your basis for perpetual motion will not work. And is the opposite
of brilliant.

Casady


Well, not quite. The harvested fresh water is actually buoyant in the
sea water. Hauling up the water is energy free. Hauling up the
container and the rope is not, however.

With suitable flotation, the container could be made neutral-buoyant,
and so hauling it up could be free also, Finally, if the rope were HD
polyethylene or something else with about 1.0 density, the rope could be
free to hoist too. It would be necessary to attach a weight greater
than the weight of water to be harvested to the container in order to
get it to sink. This weight would then be disconnected/abandoned before
hoisting the recovered water. From an energy standpoint, the investment
would be that necessary to cover the friction in the hauling apparatus,
and the the invested energy content of the abandoned weight (steel:
high, concrete: medium, rock: free).

Venting the container to the surface would be impractical. Evacuate it
instead.

With Wilbur, one must be careful to not discard the wheat with the chaff...

bob
s/v Eolian
Seattle



And how much of the time are you sailing in 500 ft deep water, which
was the original specification?

Bruce in Bangkok
(brucepaigeATgmailDOTcom)

RW Salnick October 3rd 07 04:13 PM

Potable Water - The Third Way.
 
brought forth on stone tablets:
On Tue, 02 Oct 2007 09:59:46 -0700, RW Salnick
wrote:


Richard Casady brought forth on stone tablets:

On Sat, 22 Sep 2007 17:51:56 -0400, "Wilbur Hubbard"
wrote:



When it gets full you haul it up and empty in
into your tanks. Reverse osmosis without any energy used to get it.
Ain't Wilbur brilliant?

You haul it up without using any energy to do it? Absolutely not/ It
will take a foot pound for each pound for each foot you haul it.
No your basis for perpetual motion will not work. And is the opposite
of brilliant.

Casady


Well, not quite. The harvested fresh water is actually buoyant in the
sea water. Hauling up the water is energy free. Hauling up the
container and the rope is not, however.

With suitable flotation, the container could be made neutral-buoyant,
and so hauling it up could be free also, Finally, if the rope were HD
polyethylene or something else with about 1.0 density, the rope could be
free to hoist too. It would be necessary to attach a weight greater
than the weight of water to be harvested to the container in order to
get it to sink. This weight would then be disconnected/abandoned before
hoisting the recovered water. From an energy standpoint, the investment
would be that necessary to cover the friction in the hauling apparatus,
and the the invested energy content of the abandoned weight (steel:
high, concrete: medium, rock: free).

Venting the container to the surface would be impractical. Evacuate it
instead.

With Wilbur, one must be careful to not discard the wheat with the chaff...

bob
s/v Eolian
Seattle




And how much of the time are you sailing in 500 ft deep water, which
was the original specification?

Bruce in Bangkok
(brucepaigeATgmailDOTcom)


500 feet? That's only 83 fathoms. My sailing area is Puget Sound, much
of which is 150 fathoms or more. Why? Is Thailand in a skinny water zone?

bob
s/v Eolian
Seattle

[email protected] October 4th 07 01:43 AM

Potable Water - The Third Way.
 
On Wed, 03 Oct 2007 08:13:20 -0700, RW Salnick
wrote:

brought forth on stone tablets:
On Tue, 02 Oct 2007 09:59:46 -0700, RW Salnick
wrote:


Richard Casady brought forth on stone tablets:

On Sat, 22 Sep 2007 17:51:56 -0400, "Wilbur Hubbard"
wrote:



When it gets full you haul it up and empty in
into your tanks. Reverse osmosis without any energy used to get it.
Ain't Wilbur brilliant?

You haul it up without using any energy to do it? Absolutely not/ It
will take a foot pound for each pound for each foot you haul it.
No your basis for perpetual motion will not work. And is the opposite
of brilliant.

Casady

Well, not quite. The harvested fresh water is actually buoyant in the
sea water. Hauling up the water is energy free. Hauling up the
container and the rope is not, however.

With suitable flotation, the container could be made neutral-buoyant,
and so hauling it up could be free also, Finally, if the rope were HD
polyethylene or something else with about 1.0 density, the rope could be
free to hoist too. It would be necessary to attach a weight greater
than the weight of water to be harvested to the container in order to
get it to sink. This weight would then be disconnected/abandoned before
hoisting the recovered water. From an energy standpoint, the investment
would be that necessary to cover the friction in the hauling apparatus,
and the the invested energy content of the abandoned weight (steel:
high, concrete: medium, rock: free).

Venting the container to the surface would be impractical. Evacuate it
instead.

With Wilbur, one must be careful to not discard the wheat with the chaff...

bob
s/v Eolian
Seattle




And how much of the time are you sailing in 500 ft deep water, which
was the original specification?

Bruce in Bangkok
(brucepaigeATgmailDOTcom)


500 feet? That's only 83 fathoms. My sailing area is Puget Sound, much
of which is 150 fathoms or more. Why? Is Thailand in a skinny water zone?

bob
s/v Eolian
Seattle


From Singapore north through either the Gulf of Thailand or up the
west coats of Malaysia or most of the western part of Indonesia 150
ft. of water would be deep water. Wilbur's invention isn;t going to
work very well over here.


Bruce in Bangkok
(brucepaigeATgmailDOTcom)

Mark Borgerson October 7th 07 05:54 PM

Potable Water - The Third Way.
 
In article ,
says...
On Sat, 22 Sep 2007 10:55:52 -0500, Brian Whatcott
wrote stuff
and I replied:

But what is the cheap source of getting the vacuum? I figured there
had to be a vacuum, although it was not said. But how do you get it?

Well no, he obviously hadn't figured that out. Nor can anybody figure
out what is going to hold a column of water 40 ft high as was stated in
the original post. The tubes may be 40 feet but the column of water will
be considerably less. How much less will depend on how much energy is
heating on the hot side and how much energy is cooling on the cool side.
The total amount of energy needed is not going to be any different than
any other distilling method.
Unless you have the free or cheap sources of cooling and heating at
specific temperatures this isn't going to work any better either.

-jim


SNIP


Simply put a one-way (out only) valve at the top where the two tubes
are joined. Pump water up both tubes to about 3" from the top,
displacing the air in the tubes. That will only require about
16 PSI from the pumps.

The major problem would seem to be that vigorous boiling is going
to carry over salt and contaminants from the boiling salt water unless
the tubes are large or there is some sort of debubbler on the
salt water side.

For heating and cooling, I suppose that you could use the sunny and
shady sides of a sailboat mast.

Mark Borgerson



Mark Borgerson October 7th 07 06:14 PM

Potable Water - The Third Way.
 
In article ,
says...


jim wrote:

"jim.isbell" wrote:
Ah well, another great idea skuppered by dat old devil science :-)

Bruce in Bangkok
(brucepaigeATgmailDOTcom)
A 32' column of water is a continuous vacuum pump.


This is just plain wrong. As a *unit of measure* 32 feet of water
column equals about 13.9 psi. Meaning, if you pumped a 40' column up to
a 39' height with water, equalized the headspace to atmospheric pressure
(assuming 14.7psia), sealed it, then allowed gravity to *drain* the
water column to a height of 2', the resulting pressure in the headspace
will be about 0.8psia. Now you also have 33' of empty evacuated column.

As long as you put
water (salt water) into the column it will pull down and keep a vacuum
in the top of the column.


Sorry, this makes no sense. Putting water in does not cause it to "pull
down". Yes, you have supply makeup water to maintain column height lost
to evaporation.

The fresh water distills off the top of the
sal****er column then migrates


Yes, and this "migration" is simple diffusion. *And* you have (in the
example above) 33' of column it has to diffuse through on the seawater
side, and however many feet of column on the freshwater side it has to
traverse prior to condensation. If both columns (fresh and sea) are
referenced to the same height, then the evacuated column height on both
sides will be the same, and that diffusion path will be up to 66'. That
does not happen quickly.


How do you get 33' as 1/2 of the diffusion path. I think there will be
about 33 feet of water in the column on each side---to provide the
weigth that pulls the pressure down. That would leave only about
7 feet of water vapor path on each side of the column.

I'm not sure that 'diffusion' is the proper term for the motion
of the water vapor. After all, the heat engine is providing
water vapor on one side and condensing it on the other---so there
is a net mass flow and probably a small pressure differential to
move the vapor.

Still (pun intended), you need a lot of heat to provide the energy
to evaporate the water or it will soon cool to the point where
its vapor pressure is reduced and the process slows drastically.
The fact that the water 'boils' near room temperature does not
reduce the amount of heat required to change the water from
liquid to vapor.

As has been discussed, the simple idea does not address the problems
of salt buildup in the seawater side, or the addition of dissolved
gasses to the vacuum part of the loop.

With a large enough (or double) sal****er tube you might get a
convection cell going with the cold, saltier water sinking and
pulling up warmer seawater to the top.

You could solve the dissolved gas problem by periodically pumping
both tubes up enough to displace the accumulated gases.

Now the project is getting complex enough that an RO system
starts to look attractive!


Mark Borgerson


Mark Borgerson October 7th 07 06:27 PM

Potable Water - The Third Way.
 
In article . com,
says...
I give up. My Masters degree in Physics is of no value here. My
Bachelors degree in Math is of no value here. My 20 years with the
university (retired) means nothing. Someone with an opinion (however
false) instead of facts of physical science, seems to be more able to
swing the belief of the uninformed.

I will try to explain it again.

The vacuum will hold the column of water in the tube.

Dont believe it?
Test this statement, take a simple soda straw stick in in a glass of
water put your finger over the end and lift it out. The 8" column of
water stays in the straw because of the vacuum in the top of the
straw. Now remove your finger and the water drops out. So, it
doesn't TAKE a 32' column of water, but that is the tallest column of
water that will be suspended, a simple law of physics.

Thats why a lift pump like the old rocker handle pitcher pumps have to
be replaced with either submerged or Jet pumps in deeper wells. A
lesser column WILL work however. At the top is a vacuum. If its 32
feet, thats the greatest vacuum you can create. There is salt water
on one side and fresh water on the other. The salt water will boil
earlier because of the salt content.

Now test that statement.
Put a pot on the stove and then before it comes to a boil add salt.
Voila, it begins to boil.



BZZZZT!!! FALSE!!!


Salt water DOES NOT boil at a lower temperature than fresh water. It
boils at a higher temperature. When you add salt to heated water,
it appears to boil because the water is superheated near the bottom of
the pan and the salt crystals provide "nuclei" that start the boiling
process. You can easily verify this by starting with two pans
of water, one salty and one fresh and heating them to their respective
boiling points and measuring the temperature. More explicit
instructions, aimed at middle school students are at:

http://aquarius.nasa.gov/pdfs/prop_fresh_sea.pdf


snip


Mark Borgerson






SNIP


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