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On 2007-10-08 18:17:58 -0400, Mark Borgerson said:
Getting rid of the disssolved gases in the headspace and as bubbles forming on the sides of the tube is going to be a major headache. Not a headache, an impossibility (they're not really dissolved at that point though) :-) That, and the increase in pressure due to water vapor will make this an oscillating, self-quenching system. It'll require more and more heat as the partial pressures of the non-condensables increases, and the column heights will drop as the pressure goes up, with the diffusion path increasing the whole time. I agree with that part---except for the oscillation part. I think the processes are slow enough and the thermal and physical masses are high enough that the oscillations will be damped out and you will see a slow change to equilibrium with little or no overshoot. Though I consider this whole discussion impractical, I haven't seen anyone mention that the fresh-water side will be drawn down fairly regularly. And, of course, the sea water side will be replenished from time to time. Suck hard enough on the fresh-water side and you get even better "vacuum" at the top. (Dissolved gasses are likely to be a problem, though.) Cool the fresh-water side and water vapor will condense there -- the whole point of the exercise. Thinking only momentarily on a problem that I have little interest in... if the fresh-water side is evacuated to the point that the salt-water side is slightly below the top, every once in a while (or perhaps often), the fresh-water side will be empty and only the previously-dissolved gasses evacuated. The required evacuation pumps and one-way valves sound like the problem at the moment. -- Jere Lull Tanzer 28 #4 out of Tolchester, MD Xan's new pages: http://web.mac.com/jerelull/iWeb/Xan/ Our BVI pages: http://homepage.mac.com/jerelull/BVI/ |
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